##TITLE=              31P MAS NMR spectrum of as-made AlPO-LTA (with fluoride and Kryptofix222 plus tetramethylammonium templates)
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             Schreyeck et al. Microporous Mesoporous Mater., 22, 87-106 (1998) Figure 10a
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University
##LONG DATE=          2020/07/22 06:43:09
##SOURCE REFERENCE=   LTA-31P-Schreyeck-1998-asmade
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              LTA
##NAMES=              AlPO-LTA
##NAMES=              AlPO-42
##SAMPLE DESCRIPTION= AlPO-LTA, as-made

$$Bibliographic information 
##$AUTHORS=           Schreyeck, L., Stumbe, J., Caullet, P., Mougenel, J.C., Marler, B.
##$TITLE=             The diaza-polyoxa-macrocycle 'Kryptofix222' as a new template for the synthesis of LTA-type AlPO4: Co-templating role of F- and/or (CH3)4N+ ions
##$JOURNAL=           Microporous and Mesoporous Materials
##$VOLUME=            22
##$PAGES=             87-106
##$YEAR=              1998
##$DOI=               10.1016/S1387-1811(98)00082-1
##$FIGURE=            Figure 10a

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         2
##$PEAK LABELS=        P1         P2        
##$PEAK TSITES=        T1         T1        
##$PEAK POSITIONS=    -25.8127   -18.071    
##$PEAK AREAS=         1.         1.        
##$PEAK WIDTHS=        3.08129    2.63849   
##$PEAK SHAPES=        0.11798    0.11798   
##$NUMBERING REF=     Schreyeck et al. Microporous Mesoporous Mater., 22, 87-106 (1998)
##$ASSIGN REF=        Schreyeck et al. Microporous Mesoporous Mater., 22, 87-106 (1998) Figure 10b
##$ASSIGN METHOD=     19F/31P cross polarization
##$COMMENT=           Peak assignments are based on the relative peak areas observed in a 19F/31P cross polarization experiment and the relative 19F/31P dipolar coupling constants calculated from the crystal structure

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^31P
##.OBSERVE FREQUENCY= 121.51
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     8000

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=              28.6                 
##LASTX=              -71.4                 
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            501
##FIRSTY=              0.00826              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
  28.6                0.00826              
  28.4                0.00798              
  28.2                0.00771              
  28.                 0.00765              
  27.8                0.00765              
  27.6                0.00784              
  27.4                0.00820              
  27.2                0.00843              
  27.                 0.00844              
  26.8                0.00844              
  26.6                0.00843              
  26.4                0.00845              
  26.2                0.00827              
  26.                 0.00800              
  25.8                0.00783              
  25.6                0.00762              
  25.4                0.00732              
  25.2                0.00739              
  25.                 0.00736              
  24.8                0.00691              
  24.6                0.00677              
  24.4                0.00664              
  24.2                0.00608              
  24.                 0.00548              
  23.8                0.00512              
  23.6                0.00448              
  23.4                0.00415              
  23.2                0.00395              
  23.                 0.00359              
  22.8                0.00329              
  22.6                0.00296              
  22.4                0.00255              
  22.2                0.00210              
  22.                 0.00182              
  21.8                0.00175              
  21.6                0.00232              
  21.4                0.00294              
  21.2                0.00344              
  21.                 0.00398              
  20.8                0.00415              
  20.6                0.00412              
  20.4                0.00414              
  20.2                0.00396              
  20.                 0.00375              
  19.8                0.00379              
  19.6                0.00414              
  19.4                0.00495              
  19.2                0.00587              
  19.                 0.00658              
  18.8                0.00814              
  18.6                0.01152              
  18.4                0.01461              
  18.2                0.01778              
  18.                 0.02136              
  17.8                0.02358              
  17.6                0.02412              
  17.4                0.02345              
  17.2                0.02155              
  17.                 0.01965              
  16.8                0.01724              
  16.6                0.01433              
  16.4                0.01200              
  16.2                0.01035              
  16.                 0.00864              
  15.8                0.00731              
  15.6                0.00623              
  15.4                0.00492              
  15.2                0.00369              
  15.                 0.00303              
  14.8                0.00231              
  14.6                0.00213              
  14.4                0.00274              
  14.2                0.00351              
  14.                 0.00414              
  13.8                0.00457              
  13.6                0.00471              
  13.4                0.00413              
  13.2                0.00364              
  13.                 0.00283              
  12.8                0.00218              
  12.6                0.00217              
  12.4                0.00323              
  12.2                0.00456              
  12.                 0.00567              
  11.8                0.00712              
  11.6                0.00861              
  11.4                0.01046              
  11.2                0.01218              
  11.                 0.01403              
  10.8                0.01624              
  10.6                0.01814              
  10.4                0.01994              
  10.2                0.02139              
  10.                 0.02197              
  9.8                 0.02070              
  9.6                 0.01886              
  9.4                 0.01608              
  9.2                 0.01294              
  9.                  0.01018              
  8.8                 0.00796              
  8.6                 0.00639              
  8.4                 0.00516              
  8.2                 0.00418              
  8.                  0.00296              
  7.8                 0.00150              
  7.6                 0.00068              
  7.4                 0.00061              
  7.2                 0.00059              
  7.                  0.00087              
  6.8                 0.00109              
  6.6                 0.00064              
  6.4                -0.00015              
  6.2                -0.00089              
  6.                 -0.00166              
  5.8                -0.00278              
  5.6                -0.00330              
  5.4                -0.00331              
  5.2                -0.00331              
  5.                 -0.00320              
  4.8                -0.00303              
  4.6                -0.00355              
  4.4                -0.00470              
  4.2                -0.00542              
  4.                 -0.00589              
  3.8                -0.00625              
  3.6                -0.00639              
  3.4                -0.00645              
  3.2                -0.00634              
  3.                 -0.00595              
  2.8                -0.00535              
  2.6                -0.00461              
  2.4                -0.00399              
  2.2                -0.00344              
  2.                 -0.00289              
  1.8                -0.00258              
  1.6                -0.00251              
  1.4                -0.00252              
  1.2                -0.00252              
  1.                 -0.00261              
  0.8                -0.00279              
  0.6                -0.00337              
  0.4                -0.00395              
  0.2                -0.00423              
 -0.00000            -0.00430              
 -0.2                -0.00409              
 -0.4                -0.00408              
 -0.6                -0.00400              
 -0.8                -0.00388              
 -1.                 -0.00397              
 -1.2                -0.00419              
 -1.4                -0.00458              
 -1.6                -0.00485              
 -1.8                -0.00495              
 -2.                 -0.00514              
 -2.2                -0.00550              
 -2.4                -0.00563              
 -2.6                -0.00521              
 -2.8                -0.00491              
 -3.                 -0.00470              
 -3.2                -0.00448              
 -3.4                -0.00419              
 -3.6                -0.00379              
 -3.8                -0.00343              
 -4.                 -0.00327              
 -4.2                -0.00331              
 -4.4                -0.00330              
 -4.6                -0.00330              
 -4.8                -0.00330              
 -5.                 -0.00331              
 -5.2                -0.00322              
 -5.4                -0.00291              
 -5.6                -0.00256              
 -5.8                -0.00251              
 -6.                 -0.00252              
 -6.2                -0.00244              
 -6.4                -0.00228              
 -6.6                -0.00227              
 -6.8                -0.00239              
 -7.                 -0.00272              
 -7.2                -0.00321              
 -7.4                -0.00345              
 -7.6                -0.00388              
 -7.8                -0.00388              
 -8.                 -0.00351              
 -8.2                -0.00249              
 -8.4                -0.00142              
 -8.6                -0.00086              
 -8.8                -0.00058              
 -9.                 -0.00055              
 -9.2                -0.00074              
 -9.4                -0.00099              
 -9.6                -0.00135              
 -9.8                -0.00166              
 -10.                -0.00184              
 -10.2               -0.00211              
 -10.4               -0.00182              
 -10.6               -0.00098              
 -10.8               -0.00039              
 -11.                -0.00007              
 -11.2                0.00056              
 -11.4                0.00136              
 -11.6                0.00200              
 -11.8                0.00269              
 -12.                 0.00296              
 -12.2                0.00260              
 -12.4                0.00182              
 -12.6                0.00046              
 -12.8               -0.00059              
 -13.                -0.00111              
 -13.2               -0.00197              
 -13.4               -0.00287              
 -13.6               -0.00342              
 -13.8               -0.00361              
 -14.                -0.00267              
 -14.2               -0.00113              
 -14.4                0.00066              
 -14.6                0.00449              
 -14.8                0.00971              
 -15                  0.01837              
 -15.2                0.02775              
 -15.4                0.04358              
 -15.6                0.06628              
 -15.8                0.09082              
 -16                  0.11052              
 -16.2                0.13073              
 -16.4                0.15376              
 -16.6                0.17599              
 -16.8                0.19523              
 -17                  0.21847              
 -17.2                0.24250              
 -17.4                0.25856              
 -17.6                0.27734              
 -17.8                0.29759              
 -18                  0.32080              
 -18.2                0.34284              
 -18.4                0.36748              
 -18.6                0.38210              
 -18.8                0.35019              
 -19                  0.29456              
 -19.2                0.23182              
 -19.4                0.15662              
 -19.6                0.09683              
 -19.8                0.06174              
 -20                  0.03906              
 -20.2                0.03560              
 -20.4                0.03091              
 -20.6                0.02899              
 -20.8                0.02744              
 -21                  0.02614              
 -21.2                0.02523              
 -21.4                0.02496              
 -21.6                0.02486              
 -21.8                0.02498              
 -22.                 0.02554              
 -22.2                0.02692              
 -22.4                0.02958              
 -22.6                0.03338              
 -22.8                0.04004              
 -23.                 0.04581              
 -23.2                0.05330              
 -23.4                0.06740              
 -23.6                0.08241              
 -23.8                0.10120              
 -24                  0.11941              
 -24.2                0.13898              
 -24.4                0.15739              
 -24.6                0.17258              
 -24.8                0.19056              
 -25.                 0.20802              
 -25.2                0.22793              
 -25.4                0.24819              
 -25.6                0.26428              
 -25.8                0.27969              
 -26.                 0.29580              
 -26.2                0.30111              
 -26.4                0.29336              
 -26.6                0.27440              
 -26.8                0.23540              
 -27.                 0.19561              
 -27.2                0.15668              
 -27.4                0.12078              
 -27.6                0.09061              
 -27.8                0.06018              
 -28.                 0.03517              
 -28.2                0.02164              
 -28.4                0.01596              
 -28.6                0.01238              
 -28.8                0.00836              
 -29.                 0.00709              
 -29.2                0.00593              
 -29.4                0.00519              
 -29.6                0.00413              
 -29.8                0.00298              
 -30.                 0.00228              
 -30.2                0.00164              
 -30.4                0.00057              
 -30.6               -0.00091              
 -30.8               -0.00234              
 -31.                -0.00309              
 -31.2               -0.00318              
 -31.4               -0.00309              
 -31.6               -0.00286              
 -31.8               -0.00253              
 -32.                -0.00197              
 -32.2               -0.00113              
 -32.4               -0.00039              
 -32.6               -0.00035              
 -32.8               -0.00072              
 -33.                -0.00149              
 -33.2               -0.00223              
 -33.4               -0.00288              
 -33.6               -0.00330              
 -33.8               -0.00314              
 -34.                -0.00311              
 -34.2               -0.00374              
 -34.4               -0.00444              
 -34.6               -0.00525              
 -34.8               -0.00602              
 -35                 -0.00664              
 -35.2               -0.00718              
 -35.4               -0.00704              
 -35.6               -0.00648              
 -35.8               -0.00613              
 -36.                -0.00642              
 -36.2               -0.00682              
 -36.4               -0.00739              
 -36.6               -0.00795              
 -36.8               -0.00801              
 -37.                -0.00781              
 -37.2               -0.00759              
 -37.4               -0.00713              
 -37.6               -0.00659              
 -37.8               -0.00633              
 -38.                -0.00595              
 -38.2               -0.00553              
 -38.4               -0.00489              
 -38.6               -0.00417              
 -38.8               -0.00360              
 -39.                -0.00312              
 -39.2               -0.00266              
 -39.4               -0.00251              
 -39.6               -0.00236              
 -39.8               -0.00231              
 -40.                -0.00265              
 -40.2               -0.00304              
 -40.4               -0.00360              
 -40.6               -0.00405              
 -40.8               -0.00407              
 -41.                -0.00422              
 -41.2               -0.00464              
 -41.4               -0.00492              
 -41.6               -0.00509              
 -41.8               -0.00522              
 -42.                -0.00521              
 -42.2               -0.00484              
 -42.4               -0.00437              
 -42.6               -0.00409              
 -42.8               -0.00408              
 -43.                -0.00408              
 -43.2               -0.00409              
 -43.4               -0.00406              
 -43.6               -0.00425              
 -43.8               -0.00490              
 -44.                -0.00526              
 -44.2               -0.00507              
 -44.4               -0.00490              
 -44.6               -0.00486              
 -44.8               -0.00488              
 -45.                -0.00484              
 -45.2               -0.00508              
 -45.4               -0.00573              
 -45.6               -0.00622              
 -45.8               -0.00631              
 -46.                -0.00618              
 -46.2               -0.00561              
 -46.4               -0.00501              
 -46.6               -0.00477              
 -46.8               -0.00435              
 -47.                -0.00442              
 -47.2               -0.00477              
 -47.4               -0.00489              
 -47.6               -0.00487              
 -47.8               -0.00480              
 -48.                -0.00456              
 -48.2               -0.00434              
 -48.4               -0.00411              
 -48.6               -0.00408              
 -48.8               -0.00417              
 -49.                -0.00439              
 -49.2               -0.00470              
 -49.4               -0.00506              
 -49.6               -0.00555              
 -49.8               -0.00567              
 -50.                -0.00549              
 -50.2               -0.00494              
 -50.4               -0.00444              
 -50.6               -0.00416              
 -50.8               -0.00413              
 -51.                -0.00450              
 -51.2               -0.00508              
 -51.4               -0.00596              
 -51.6               -0.00637              
 -51.8               -0.00640              
 -52.                -0.00607              
 -52.2               -0.00566              
 -52.4               -0.00525              
 -52.6               -0.00465              
 -52.8               -0.00411              
 -53.                -0.00391              
 -53.2               -0.00301              
 -53.4               -0.00161              
 -53.6                0.00066              
 -53.8                0.00335              
 -54.                 0.00626              
 -54.2                0.00835              
 -54.4                0.00991              
 -54.6                0.01074              
 -54.8                0.01100              
 -55.                 0.01066              
 -55.2                0.01009              
 -55.4                0.00958              
 -55.6                0.00887              
 -55.8                0.00734              
 -56.                 0.00501              
 -56.2                0.00298              
 -56.4                0.00127              
 -56.6               -0.00050              
 -56.8               -0.00162              
 -57.                -0.00236              
 -57.2               -0.00286              
 -57.4               -0.00310              
 -57.6               -0.00309              
 -57.8               -0.00271              
 -58.                -0.00192              
 -58.2               -0.00127              
 -58.4               -0.00100              
 -58.6               -0.00096              
 -58.8               -0.00093              
 -59.                -0.00140              
 -59.2               -0.00198              
 -59.4               -0.00242              
 -59.6               -0.00234              
 -59.8               -0.00134              
 -60.                -0.00020              
 -60.2                0.00073              
 -60.4                0.00117              
 -60.6                0.00135              
 -60.8                0.00214              
 -61.                 0.00320              
 -61.2                0.00533              
 -61.4                0.00881              
 -61.6                0.01008              
 -61.8                0.01154              
 -62.                 0.01227              
 -62.2                0.01216              
 -62.4                0.01128              
 -62.6                0.01026              
 -62.8                0.00906              
 -63.                 0.00765              
 -63.2                0.00675              
 -63.4                0.00562              
 -63.6                0.00427              
 -63.8                0.00296              
 -64.                 0.00203              
 -64.2                0.00126              
 -64.4               -0.00024              
 -64.6               -0.00131              
 -64.8               -0.00129              
 -65.                -0.00111              
 -65.2               -0.00106              
 -65.4               -0.00136              
 -65.6               -0.00211              
 -65.8               -0.00258              
 -66.                -0.00336              
 -66.2               -0.00408              
 -66.4               -0.00401              
 -66.6               -0.00380              
 -66.8               -0.00324              
 -67.                -0.00262              
 -67.2               -0.00260              
 -67.4               -0.00303              
 -67.6               -0.00346              
 -67.8               -0.00402              
 -68.                -0.00457              
 -68.2               -0.00520              
 -68.4               -0.00616              
 -68.6               -0.00698              
 -68.8               -0.00675              
 -69.                -0.00628              
 -69.2               -0.00590              
 -69.4               -0.00566              
 -69.6               -0.00564              
 -69.8               -0.00570              
 -70.                -0.00607              
 -70.2               -0.00641              
 -70.4               -0.00630              
 -70.6               -0.00566              
 -70.8               -0.00531              
 -71.                -0.00525              
 -71.2               -0.00526              
 -71.4               -0.00526              
##END=
