##TITLE=              29Si MAS NMR spectrum of calcined dealuminated ZSM-18
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             Schmitt and Kennedy. Zeolites, 14, 635-642 (1994) Figure 4
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University College
##LONG DATE=          2019/08/08 14:45:00
##SOURCE REFERENCE=   MEI-29Si-Schmitt-1994
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              MEI
##NAMES=              ZSM-18
##SAMPLE DESCRIPTION= ZSM-18, dealuminated

$$Bibliographic information 
##$AUTHORS=           Schmitt, K.D., Kennedy, G.J.
##$TITLE=             Toward the rational design of zeolite synthesis: the synthesis of zeolite ZSM-18
##$JOURNAL=           Zeolites
##$VOLUME=            14
##$PAGES=             635-642
##$YEAR=              1994
##$DOI=               10.1016/0144-2449(94)90120-1
##$FIGURE=            Figure 4

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         4
##$PEAK LABELS=        Si1        Si3        Si2        Si4       
##$PEAK TSITES=        T4         T2         T1         T3        
##$PEAK POSITIONS=    -113.683   -109.234   -109.226   -104.266   
##$PEAK AREAS=         2.         6.         6.         3.        
##$PEAK WIDTHS=        1.34361    2.17676    2.17676    1.76061   
##$PEAK SHAPES=        1          1          1          1         
##$NUMBERING REF=     Lawton and Rohrbaugh, Science, 247, 1319-1321, (1990)
##$ASSIGN REF=        Schmitt and Kennedy. Zeolites, 14, 635-642 (1994) Table 1
##$ASSIGN METHOD=     relative intensities
##$COMMENT=           

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^29Si
##.OBSERVE FREQUENCY= 79.47
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     5000

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=             -50.8                 
##LASTX=              -146.8                
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            1201
##FIRSTY=             -0.01104              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
 -50.8               -0.01104              
 -50.88              -0.01104              
 -50.96              -0.01104              
 -51.04              -0.01104              
 -51.12              -0.01104              
 -51.2               -0.01104              
 -51.28              -0.01104              
 -51.36              -0.01104              
 -51.44              -0.01104              
 -51.52              -0.01104              
 -51.6               -0.01104              
 -51.68              -0.01104              
 -51.76              -0.01104              
 -51.84              -0.01104              
 -51.92              -0.01104              
 -52.                -0.01104              
 -52.08              -0.01104              
 -52.16              -0.01104              
 -52.24              -0.01104              
 -52.32              -0.01104              
 -52.4               -0.01104              
 -52.48              -0.01104              
 -52.56              -0.01104              
 -52.64              -0.01104              
 -52.72              -0.01104              
 -52.8               -0.01104              
 -52.88              -0.01104              
 -52.96              -0.01104              
 -53.04              -0.01104              
 -53.12              -0.01104              
 -53.2               -0.01104              
 -53.28              -0.01104              
 -53.36              -0.01104              
 -53.44              -0.01104              
 -53.52              -0.01104              
 -53.6               -0.01104              
 -53.68              -0.01104              
 -53.76              -0.01104              
 -53.84              -0.01104              
 -53.92              -0.01104              
 -54.                -0.01104              
 -54.08              -0.01104              
 -54.16              -0.01104              
 -54.24              -0.01104              
 -54.32              -0.01104              
 -54.4               -0.01104              
 -54.48              -0.01104              
 -54.56              -0.01104              
 -54.64              -0.01104              
 -54.72              -0.01104              
 -54.8               -0.01104              
 -54.88              -0.01104              
 -54.96              -0.01104              
 -55.04              -0.01104              
 -55.12              -0.01104              
 -55.2               -0.01104              
 -55.28              -0.01104              
 -55.36              -0.01104              
 -55.44              -0.01104              
 -55.52              -0.01104              
 -55.6               -0.01104              
 -55.68              -0.01104              
 -55.76              -0.01104              
 -55.84              -0.01104              
 -55.92              -0.01104              
 -56.                -0.01104              
 -56.08              -0.01104              
 -56.16              -0.01104              
 -56.24              -0.01104              
 -56.32              -0.01104              
 -56.4               -0.01104              
 -56.48              -0.01104              
 -56.56              -0.01104              
 -56.64              -0.01104              
 -56.72              -0.01104              
 -56.8               -0.01104              
 -56.88              -0.01104              
 -56.96              -0.01104              
 -57.04              -0.01105              
 -57.12              -0.01102              
 -57.2               -0.01114              
 -57.28              -0.01069              
 -57.36              -0.01235              
 -57.44              -0.00387              
 -57.52               0.00299              
 -57.6               -0.00015              
 -57.68               0.00863              
 -57.76               0.01516              
 -57.84               0.01374              
 -57.92               0.01396              
 -58.                 0.01450              
 -58.08               0.01118              
 -58.16               0.00429              
 -58.24              -0.00160              
 -58.32              -0.00853              
 -58.4               -0.01153              
 -58.48              -0.01090              
 -58.56              -0.01111              
 -58.64              -0.01091              
 -58.72              -0.01149              
 -58.8               -0.00865              
 -58.88              -0.00100              
 -58.96               0.00150              
 -59.04               0.00371              
 -59.12               0.01126              
 -59.2                0.01480              
 -59.28               0.01270              
 -59.36               0.01966              
 -59.44               0.02788              
 -59.52               0.02611              
 -59.6                0.02695              
 -59.68               0.02537              
 -59.76               0.03183              
 -59.84               0.04042              
 -59.92               0.03870              
 -60.                 0.03926              
 -60.08               0.03874              
 -60.16               0.04026              
 -60.24               0.03393              
 -60.32               0.02626              
 -60.4                0.02222              
 -60.48               0.01243              
 -60.56               0.01492              
 -60.64               0.01165              
 -60.72               0.00709              
 -60.8                0.00796              
 -60.88               0.00757              
 -60.96               0.00826              
 -61.04               0.00563              
 -61.12               0.00088              
 -61.2                0.00141              
 -61.28               0.00237              
 -61.36              -0.00242              
 -61.44              -0.01238              
 -61.52              -0.01068              
 -61.6               -0.01116              
 -61.68              -0.01093              
 -61.76              -0.01137              
 -61.84              -0.00968              
 -61.92              -0.00244              
 -62.                 0.00218              
 -62.08               0.00056              
 -62.16               0.00475              
 -62.24               0.01549              
 -62.32               0.01296              
 -62.4                0.01700              
 -62.48               0.02853              
 -62.56               0.02325              
 -62.64               0.01285              
 -62.72               0.01432              
 -62.8                0.01393              
 -62.88               0.01404              
 -62.96               0.01401              
 -63.04               0.01402              
 -63.12               0.01400              
 -63.2                0.01406              
 -63.28               0.01385              
 -63.36               0.01467              
 -63.44               0.02288              
 -63.52               0.03484              
 -63.6                0.03970              
 -63.68               0.04880              
 -63.76               0.06646              
 -63.84               0.07143              
 -63.92               0.07767              
 -64.                 0.08515              
 -64.08               0.09674              
 -64.16               0.10422              
 -64.24               0.12372              
 -64.32               0.13358              
 -64.4                0.13331              
 -64.48               0.14144              
 -64.56               0.15262              
 -64.64               0.15183              
 -64.72               0.15136              
 -64.8                0.14468              
 -64.88               0.13836              
 -64.96               0.13287              
 -65.04               0.13274              
 -65.12               0.12578              
 -65.2                0.12044              
 -65.28               0.12002              
 -65.36               0.11418              
 -65.44               0.11342              
 -65.52               0.10110              
 -65.6                0.10180              
 -65.68               0.10213              
 -65.76               0.10025              
 -65.84               0.07553              
 -65.92               0.07713              
 -66.                 0.07601              
 -66.08               0.06362              
 -66.16               0.06454              
 -66.24               0.06315              
 -66.32               0.03832              
 -66.4                0.03932              
 -66.48               0.03886              
 -66.56               0.03269              
 -66.64               0.03285              
 -66.72               0.03281              
 -66.8                0.03282              
 -66.88               0.03281              
 -66.96               0.03281              
 -67.04               0.03281              
 -67.12               0.03281              
 -67.2                0.03281              
 -67.28               0.03281              
 -67.36               0.03281              
 -67.44               0.03281              
 -67.52               0.03281              
 -67.6                0.03281              
 -67.68               0.03281              
 -67.76               0.03281              
 -67.84               0.03281              
 -67.92               0.03282              
 -68.                 0.03281              
 -68.08               0.03283              
 -68.16               0.03276              
 -68.24               0.03303              
 -68.32               0.02683              
 -68.4                0.02647              
 -68.48               0.02658              
 -68.56               0.02653              
 -68.64               0.02661              
 -68.72               0.02633              
 -68.8                0.03207              
 -68.88               0.03878              
 -68.96               0.03908              
 -69.04               0.03941              
 -69.12               0.03332              
 -69.2                0.03277              
 -69.28               0.02820              
 -69.36               0.00978              
 -69.44               0.00158              
 -69.52               0.00173              
 -69.6               -0.00364              
 -69.68              -0.01061              
 -69.76              -0.01085              
 -69.84              -0.01606              
 -69.92              -0.02301              
 -70.                -0.02372              
 -70.08              -0.02353              
 -70.16              -0.02359              
 -70.24              -0.02357              
 -70.32              -0.02358              
 -70.4               -0.02357              
 -70.48              -0.02357              
 -70.56              -0.02357              
 -70.64              -0.02357              
 -70.72              -0.02357              
 -70.8               -0.02357              
 -70.88              -0.02357              
 -70.96              -0.02357              
 -71.04              -0.02357              
 -71.12              -0.02357              
 -71.2               -0.02357              
 -71.28              -0.02357              
 -71.36              -0.02357              
 -71.44              -0.02357              
 -71.52              -0.02357              
 -71.6               -0.02357              
 -71.68              -0.02357              
 -71.76              -0.02357              
 -71.84              -0.02357              
 -71.92              -0.02357              
 -72.                -0.02357              
 -72.08              -0.02357              
 -72.16              -0.02357              
 -72.24              -0.02357              
 -72.32              -0.02357              
 -72.4               -0.02357              
 -72.48              -0.02357              
 -72.56              -0.02357              
 -72.64              -0.02357              
 -72.72              -0.02357              
 -72.8               -0.02357              
 -72.88              -0.02357              
 -72.96              -0.02357              
 -73.04              -0.02357              
 -73.12              -0.02357              
 -73.2               -0.02357              
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 -73.36              -0.02357              
 -73.44              -0.02357              
 -73.52              -0.02357              
 -73.6               -0.02357              
 -73.68              -0.02357              
 -73.76              -0.02357              
 -73.84              -0.02357              
 -73.92              -0.02357              
 -74.                -0.02357              
 -74.08              -0.02357              
 -74.16              -0.02357              
 -74.24              -0.02357              
 -74.32              -0.02358              
 -74.4               -0.02357              
 -74.48              -0.02358              
 -74.56              -0.02355              
 -74.64              -0.02367              
 -74.72              -0.02322              
 -74.8               -0.02490              
 -74.88              -0.01650              
 -74.96              -0.00990              
 -75.04              -0.01124              
 -75.12              -0.01141              
 -75.2               -0.00841              
 -75.28              -0.00045              
 -75.36               0.00063              
 -75.44               0.00796              
 -75.52               0.01524              
 -75.6                0.01384              
 -75.68               0.01348              
 -75.76               0.01711              
 -75.84               0.02105              
 -75.92               0.01961              
 -76.                 0.02219              
 -76.08               0.01122              
 -76.16              -0.00044              
 -76.24               0.00200              
 -76.32               0.00134              
 -76.4                0.00152              
 -76.48               0.00147              
 -76.56               0.00148              
 -76.64               0.00148              
 -76.72               0.00148              
 -76.8                0.00148              
 -76.88               0.00148              
 -76.96               0.00148              
 -77.04               0.00149              
 -77.12               0.00146              
 -77.2                0.00156              
 -77.28               0.00119              
 -77.36               0.00257              
 -77.44              -0.00335              
 -77.52              -0.01249              
 -77.6               -0.01030              
 -77.68              -0.01292              
 -77.76              -0.02036              
 -77.84              -0.02368              
 -77.92              -0.02524              
 -78.                -0.03249              
 -78.08              -0.03757              
 -78.16              -0.03178              
 -78.24              -0.02201              
 -78.32              -0.02487              
 -78.4               -0.01948              
 -78.48              -0.00947              
 -78.56              -0.01232              
 -78.64              -0.00708              
 -78.72               0.00279              
 -78.8                0.00113              
 -78.88               0.00158              
 -78.96               0.00146              
 -79.04               0.00149              
 -79.12               0.00148              
 -79.2                0.00148              
 -79.28               0.00150              
 -79.36               0.00140              
 -79.44               0.00177              
 -79.52               0.00027              
 -79.6               -0.00691              
 -79.68              -0.01170              
 -79.76              -0.01019              
 -79.84              -0.01399              
 -79.92              -0.02481              
 -80.                -0.02325              
 -80.08              -0.02366              
 -80.16              -0.02357              
 -80.24              -0.02352              
 -80.32              -0.02379              
 -80.4               -0.02269              
 -80.48              -0.01535              
 -80.56              -0.01122              
 -80.64              -0.00885              
 -80.72               0.00264              
 -80.8                0.00117              
 -80.88               0.00156              
 -80.96               0.00146              
 -81.04               0.00149              
 -81.12               0.00148              
 -81.2                0.00148              
 -81.28               0.00148              
 -81.36               0.00148              
 -81.44               0.00148              
 -81.52               0.00147              
 -81.6                0.00152              
 -81.68               0.00133              
 -81.76               0.00205              
 -81.84               0.00891              
 -81.92               0.01440              
 -82.                 0.01371              
 -82.08               0.01486              
 -82.16               0.02008              
 -82.24               0.01343              
 -82.32               0.01444              
 -82.4                0.01290              
 -82.48               0.00068              
 -82.56               0.00196              
 -82.64               0.00039              
 -82.72              -0.01135              
 -82.8               -0.00387              
 -82.88               0.00166              
 -82.96               0.00144              
 -83.04               0.00149              
 -83.12               0.00148              
 -83.2                0.00148              
 -83.28               0.00148              
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 -83.44               0.00148              
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 -83.6                0.00148              
 -83.68               0.00148              
 -83.76               0.00148              
 -83.84               0.00148              
 -83.92               0.00148              
 -84.                 0.00148              
 -84.08               0.00149              
 -84.16               0.00145              
 -84.24               0.00156              
 -84.32               0.01406              
 -84.4                0.01401              
 -84.48               0.01401              
 -84.56               0.01402              
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 -84.72               0.01407              
 -84.8                0.00793              
 -84.88               0.00156              
 -84.96               0.00146              
 -85.04               0.00149              
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 -85.2                0.00148              
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 -85.6                0.00148              
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 -86.                 0.00148              
 -86.08               0.00148              
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 -88.                 0.00148              
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 -88.72              -0.01086              
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 -89.04              -0.01113              
 -89.12              -0.01071              
 -89.2               -0.01229              
 -89.28              -0.00174              
 -89.36               0.00260              
 -89.44              -0.00001              
 -89.52               0.01074              
 -89.6                0.01481              
 -89.68               0.01383              
 -89.76               0.01394              
 -89.84               0.01449              
 -89.92               0.01022              
 -90.                 0.00299              
 -90.08               0.00080              
 -90.16               0.00291              
 -90.24              -0.00715              
 -90.32              -0.01197              
 -90.4               -0.01079              
 -90.48              -0.01111              
 -90.56              -0.01102              
 -90.64              -0.01105              
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 -91.04              -0.01104              
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 -91.2               -0.01102              
 -91.28              -0.01114              
 -91.36              -0.01069              
 -91.44              -0.01236              
 -91.52              -0.00359              
 -91.6                0.00294              
 -91.68              -0.00012              
 -91.76               0.00881              
 -91.84               0.01549              
 -91.92               0.01238              
 -92.                 0.02124              
 -92.08               0.02769              
 -92.16               0.02623              
 -92.24               0.02666              
 -92.32               0.02643              
 -92.4                0.02691              
 -92.48               0.02521              
 -92.56               0.03334              
 -92.64               0.03983              
 -92.72               0.04139              
 -92.8                0.04922              
 -92.88               0.05230              
 -92.96               0.05057              
 -93.04               0.05663              
 -93.12               0.07158              
 -93.2                0.07762              
 -93.28               0.07643              
 -93.36               0.07675              
 -93.44               0.07667              
 -93.52               0.07664              
 -93.6                0.07684              
 -93.68               0.07608              
 -93.76               0.07949              
 -93.84               0.08361              
 -93.92               0.08277              
 -94.                 0.08299              
 -94.08               0.08293              
 -94.16               0.08295              
 -94.24               0.08295              
 -94.32               0.08295              
 -94.4                0.08295              
 -94.48               0.08295              
 -94.56               0.08295              
 -94.64               0.08295              
 -94.72               0.08294              
 -94.8                0.08296              
 -94.88               0.08291              
 -94.96               0.08309              
 -95.04               0.08243              
 -95.12               0.08518              
 -95.2                0.08988              
 -95.28               0.08907              
 -95.36               0.08913              
 -95.44               0.08969              
 -95.52               0.08715              
 -95.6                0.08228              
 -95.68               0.08310              
 -95.76               0.08299              
 -95.84               0.08263              
 -95.92               0.08440              
 -96.                 0.09175              
 -96.08               0.09597              
 -96.16               0.09535              
 -96.24               0.09551              
 -96.32               0.09547              
 -96.4                0.09548              
 -96.48               0.09549              
 -96.56               0.09543              
 -96.64               0.09567              
 -96.72               0.09478              
 -96.8                0.09831              
 -96.88               0.11043              
 -96.96               0.11606              
 -97.04               0.12109              
 -97.12               0.12040              
 -97.2                0.12059              
 -97.28               0.12051              
 -97.36               0.12064              
 -97.44               0.12023              
 -97.52               0.12180              
 -97.6                0.12749              
 -97.68               0.12635              
 -97.76               0.12805              
 -97.84               0.13360              
 -97.92               0.13307              
 -98.                 0.13262              
 -98.08               0.13499              
 -98.16               0.14755              
 -98.24               0.15287              
 -98.32               0.15963              
 -98.4                0.16469              
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##END=
