##TITLE=              29Si MAS NMR spectrum of dealuminated TNU-9
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             Hong et al. J. Am. Chem. Soc., 129, 10870-10885 (2007) Figure 11c
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University College
##LONG DATE=          2019/08/08 15:34:27
##SOURCE REFERENCE=   TUN-29Si-Hong-2007
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              TUN
##NAMES=              TNU-9
##SAMPLE DESCRIPTION= TNU-9, dealuminated

$$Bibliographic information 
##$AUTHORS=           Hong, S.B., Min, H., Shin, C., Cox, P.A., Warrender, S.J., Wright, P.A.
##$TITLE=             Synthesis, Crystal Structure, Characterization, and Catalytic Properties of TNU-9
##$JOURNAL=           Journal of the American Chemical Society
##$VOLUME=            129
##$PAGES=             10870-10885
##$YEAR=              2007
##$DOI=               10.1021/ja073109g
##$FIGURE=            Figure 11c

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         24
##$PEAK LABELS=        A          B          C          D          E          F          H          G          I          J          K          L          M          N          O          P          Q          S          R          T          U          V          X          W         
##$PEAK TSITES=       
##$PEAK POSITIONS=    -116.014   -115.802   -115.104   -114.824   -114.746   -114.239   -113.899   -113.899   -113.623   -113.544   -113.478   -113.265   -112.991   -112.991   -112.753   -112.548   -112.319   -112.106   -112.106   -111.286   -110.251   -109.612   -108.669   -108.594   
##$PEAK AREAS=         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.        
##$PEAK WIDTHS=        0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631    0.69631   
##$PEAK SHAPES=        1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1         
##$NUMBERING REF=     
##$ASSIGN REF=        
##$ASSIGN METHOD=     
##$COMMENT=           

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^29Si
##.OBSERVE FREQUENCY= 99.352
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     10000

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=             -100.12               
##LASTX=              -124.88               
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            620
##FIRSTY=              0.12668              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
 -100.12              0.12668              
 -100.16              0.12397              
 -100.2               0.11764              
 -100.24              0.12318              
 -100.28              0.12996              
 -100.32              0.12814              
 -100.36              0.12565              
 -100.4               0.11396              
 -100.44              0.10812              
 -100.48              0.11699              
 -100.52              0.11994              
 -100.56              0.10647              
 -100.6               0.08732              
 -100.64              0.06983              
 -100.68              0.05531              
 -100.72              0.04714              
 -100.76              0.05239              
 -100.8               0.07131              
 -100.84              0.09502              
 -100.88              0.10912              
 -100.92              0.11047              
 -100.96              0.10853              
 -101.                0.10796              
 -101.04              0.11225              
 -101.08              0.12086              
 -101.12              0.12076              
 -101.16              0.11260              
 -101.2               0.10292              
 -101.24              0.09447              
 -101.28              0.09118              
 -101.32              0.10137              
 -101.36              0.11678              
 -101.4               0.12754              
 -101.44              0.12315              
 -101.48              0.09856              
 -101.52              0.07865              
 -101.56              0.06349              
 -101.6               0.04561              
 -101.64              0.03609              
 -101.68              0.03335              
 -101.72              0.04150              
 -101.76              0.05202              
 -101.8               0.05589              
 -101.84              0.06207              
 -101.88              0.06921              
 -101.92              0.07615              
 -101.96              0.07914              
 -102.                0.08670              
 -102.04              0.09292              
 -102.08              0.09452              
 -102.12              0.09093              
 -102.16              0.08619              
 -102.2               0.07681              
 -102.24              0.06441              
 -102.28              0.05942              
 -102.32              0.06086              
 -102.36              0.07094              
 -102.4               0.07885              
 -102.44              0.07772              
 -102.48              0.06756              
 -102.52              0.05964              
 -102.56              0.06837              
 -102.6               0.07360              
 -102.64              0.07916              
 -102.68              0.09079              
 -102.72              0.09231              
 -102.76              0.08818              
 -102.8               0.07704              
 -102.84              0.05720              
 -102.88              0.03783              
 -102.92              0.03057              
 -102.96              0.04110              
 -103.                0.06097              
 -103.04              0.07729              
 -103.08              0.10192              
 -103.12              0.11980              
 -103.16              0.12951              
 -103.2               0.12526              
 -103.24              0.11187              
 -103.28              0.1042               
 -103.32              0.09737              
 -103.36              0.09860              
 -103.4               0.10924              
 -103.44              0.12457              
 -103.48              0.13672              
 -103.52              0.14009              
 -103.56              0.13461              
 -103.6               0.12957              
 -103.64              0.12282              
 -103.68              0.10766              
 -103.72              0.09717              
 -103.76              0.09087              
 -103.8               0.08231              
 -103.84              0.07877              
 -103.88              0.08427              
 -103.92              0.09196              
 -103.96              0.09974              
 -104.                0.10339              
 -104.04              0.10648              
 -104.08              0.11384              
 -104.12              0.11721              
 -104.16              0.12537              
 -104.2               0.13109              
 -104.24              0.12869              
 -104.28              0.12018              
 -104.32              0.10601              
 -104.36              0.10474              
 -104.4               0.11100              
 -104.44              0.11849              
 -104.48              0.12656              
 -104.52              0.12740              
 -104.56              0.12211              
 -104.6               0.12108              
 -104.64              0.12053              
 -104.68              0.12903              
 -104.72              0.14109              
 -104.76              0.15264              
 -104.8               0.15569              
 -104.84              0.14953              
 -104.88              0.14503              
 -104.92              0.13995              
 -104.96              0.13402              
 -105.                0.13210              
 -105.04              0.13472              
 -105.08              0.13808              
 -105.12              0.14551              
 -105.16              0.15316              
 -105.2               0.15617              
 -105.24              0.15523              
 -105.28              0.15433              
 -105.32              0.15468              
 -105.36              0.15894              
 -105.4               0.16044              
 -105.44              0.15924              
 -105.48              0.15875              
 -105.52              0.15759              
 -105.56              0.15393              
 -105.6               0.14894              
 -105.64              0.14771              
 -105.68              0.15117              
 -105.72              0.15488              
 -105.76              0.16323              
 -105.8               0.16904              
 -105.84              0.16150              
 -105.88              0.15479              
 -105.92              0.15670              
 -105.96              0.17029              
 -106.                0.18900              
 -106.04              0.20330              
 -106.08              0.20806              
 -106.12              0.19796              
 -106.16              0.18395              
 -106.2               0.17444              
 -106.24              0.17820              
 -106.28              0.19043              
 -106.32              0.20322              
 -106.36              0.21932              
 -106.4               0.22999              
 -106.44              0.23639              
 -106.48              0.23854              
 -106.52              0.24606              
 -106.56              0.25662              
 -106.6               0.25947              
 -106.64              0.25585              
 -106.68              0.25169              
 -106.72              0.23926              
 -106.76              0.22999              
 -106.8               0.24248              
 -106.84              0.25477              
 -106.88              0.26530              
 -106.92              0.26167              
 -106.96              0.25148              
 -107.                0.23508              
 -107.04              0.23474              
 -107.08              0.25056              
 -107.12              0.26971              
 -107.16              0.29180              
 -107.2               0.30807              
 -107.24              0.29407              
 -107.28              0.26803              
 -107.32              0.25493              
 -107.36              0.25598              
 -107.4               0.27412              
 -107.44              0.29472              
 -107.48              0.31718              
 -107.52              0.34038              
 -107.56              0.35202              
 -107.6               0.35892              
 -107.64              0.36530              
 -107.68              0.37382              
 -107.72              0.38696              
 -107.76              0.40706              
 -107.8               0.42049              
 -107.84              0.42870              
 -107.88              0.44991              
 -107.92              0.46986              
 -107.96              0.48880              
 -108.                0.52653              
 -108.04              0.57727              
 -108.08              0.61899              
 -108.12              0.69507              
 -108.16              0.79632              
 -108.2               0.89852              
 -108.24              1.02178              
 -108.28              1.17369              
 -108.32              1.32072              
 -108.36              1.48556              
 -108.4               1.63369              
 -108.44              1.75827              
 -108.48              1.90676              
 -108.52              2.00255              
 -108.56              2.05113              
 -108.6               2.11411              
 -108.64              2.11979              
 -108.68              2.06177              
 -108.72              1.99392              
 -108.76              1.92165              
 -108.8               1.83703              
 -108.84              1.73415              
 -108.88              1.63843              
 -108.92              1.57771              
 -108.96              1.48638              
 -109.                1.37914              
 -109.04              1.31649              
 -109.08              1.25211              
 -109.12              1.18583              
 -109.16              1.14793              
 -109.2               1.14727              
 -109.24              1.17127              
 -109.28              1.21479              
 -109.32              1.27054              
 -109.36              1.34448              
 -109.4               1.4444               
 -109.44              1.52363              
 -109.48              1.57088              
 -109.52              1.64031              
 -109.56              1.70329              
 -109.6               1.71853              
 -109.64              1.69787              
 -109.68              1.65899              
 -109.72              1.63052              
 -109.76              1.60585              
 -109.8               1.57381              
 -109.84              1.53831              
 -109.88              1.50315              
 -109.92              1.47227              
 -109.96              1.45371              
 -110.                1.46541              
 -110.04              1.49469              
 -110.08              1.51141              
 -110.12              1.5333               
 -110.16              1.54564              
 -110.2               1.54423              
 -110.24              1.54442              
 -110.28              1.54529              
 -110.32              1.54752              
 -110.36              1.53944              
 -110.4               1.51318              
 -110.44              1.46274              
 -110.48              1.41159              
 -110.52              1.35262              
 -110.56              1.30176              
 -110.6               1.25863              
 -110.64              1.20897              
 -110.68              1.17894              
 -110.72              1.16022              
 -110.76              1.15194              
 -110.8               1.15861              
 -110.84              1.1819               
 -110.88              1.2099               
 -110.92              1.25372              
 -110.96              1.30654              
 -111.                1.3637               
 -111.04              1.43846              
 -111.08              1.50722              
 -111.12              1.57196              
 -111.16              1.65897              
 -111.2               1.7386               
 -111.24              1.79277              
 -111.28              1.85227              
 -111.32              1.89464              
 -111.36              1.91469              
 -111.4               1.92318              
 -111.44              1.91559              
 -111.48              1.90009              
 -111.52              1.88881              
 -111.56              1.89926              
 -111.6               1.92399              
 -111.64              1.97984              
 -111.68              2.07976              
 -111.72              2.19772              
 -111.76              2.32197              
 -111.8               2.45623              
 -111.84              2.68674              
 -111.88              2.88029              
 -111.92              3.05379              
 -111.96              3.2571               
 -112.                3.46007              
 -112.04              3.66429              
 -112.08              3.85512              
 -112.12              4.01321              
 -112.16              4.13831              
 -112.2               4.21764              
 -112.24              4.26975              
 -112.28              4.33918              
 -112.32              4.38401              
 -112.36              4.39801              
 -112.4               4.41694              
 -112.44              4.43886              
 -112.48              4.46105              
 -112.52              4.4963               
 -112.56              4.53975              
 -112.6               4.58112              
 -112.64              4.64458              
 -112.68              4.72212              
 -112.72              4.77377              
 -112.76              4.83154              
 -112.8               4.90697              
 -112.84              4.95942              
 -112.88              5.02166              
 -112.92              5.08889              
 -112.96              5.13419              
 -113.                5.16874              
 -113.04              5.18894              
 -113.08              5.19617              
 -113.12              5.2028               
 -113.16              5.20094              
 -113.2               5.19635              
 -113.24              5.21273              
 -113.28              5.27766              
 -113.32              5.34445              
 -113.36              5.40732              
 -113.4               5.4824               
 -113.44              5.52756              
 -113.48              5.56702              
 -113.52              5.59281              
 -113.56              5.58661              
 -113.6               5.54741              
 -113.64              5.4922               
 -113.68              5.42014              
 -113.72              5.34195              
 -113.76              5.24186              
 -113.8               5.13634              
 -113.84              5.04143              
 -113.88              4.90493              
 -113.92              4.77479              
 -113.96              4.66584              
 -114.                4.49169              
 -114.04              4.35794              
 -114.08              4.2266               
 -114.12              4.06479              
 -114.16              3.90905              
 -114.2               3.75214              
 -114.24              3.61736              
 -114.28              3.53289              
 -114.32              3.42797              
 -114.36              3.3411               
 -114.4               3.29651              
 -114.44              3.24959              
 -114.48              3.22108              
 -114.52              3.23955              
 -114.56              3.27436              
 -114.6               3.31907              
 -114.64              3.36556              
 -114.68              3.40128              
 -114.72              3.44365              
 -114.76              3.48594              
 -114.8               3.49468              
 -114.84              3.48386              
 -114.88              3.4376               
 -114.92              3.35698              
 -114.96              3.27505              
 -115.                3.16831              
 -115.04              3.05842              
 -115.08              2.95057              
 -115.12              2.82544              
 -115.16              2.69245              
 -115.2               2.57133              
 -115.24              2.44949              
 -115.28              2.32998              
 -115.32              2.2452               
 -115.36              2.15153              
 -115.4               2.07427              
 -115.44              2.01179              
 -115.48              1.98465              
 -115.52              2.01212              
 -115.56              2.04618              
 -115.6               2.09457              
 -115.64              2.16798              
 -115.68              2.23819              
 -115.72              2.29333              
 -115.76              2.34674              
 -115.8               2.40359              
 -115.84              2.42231              
 -115.88              2.3879               
 -115.92              2.33151              
 -115.96              2.22667              
 -116.                2.14023              
 -116.04              2.06061              
 -116.08              1.94657              
 -116.12              1.83582              
 -116.16              1.72793              
 -116.2               1.61109              
 -116.24              1.48082              
 -116.28              1.36708              
 -116.32              1.26808              
 -116.36              1.16613              
 -116.4               1.09651              
 -116.44              1.03323              
 -116.48              0.94904              
 -116.52              0.89538              
 -116.56              0.85244              
 -116.6               0.79787              
 -116.64              0.75552              
 -116.68              0.72538              
 -116.72              0.70355              
 -116.76              0.68442              
 -116.8               0.66670              
 -116.84              0.64174              
 -116.88              0.61369              
 -116.92              0.59610              
 -116.96              0.56965              
 -117.                0.54044              
 -117.04              0.50732              
 -117.08              0.47930              
 -117.12              0.46391              
 -117.16              0.44649              
 -117.2               0.42657              
 -117.24              0.41250              
 -117.28              0.40079              
 -117.32              0.40199              
 -117.36              0.41185              
 -117.4               0.40958              
 -117.44              0.39646              
 -117.48              0.38478              
 -117.52              0.36549              
 -117.56              0.34886              
 -117.6               0.34982              
 -117.64              0.35025              
 -117.68              0.34561              
 -117.72              0.33110              
 -117.76              0.30989              
 -117.8               0.29080              
 -117.84              0.27976              
 -117.88              0.27625              
 -117.92              0.27742              
 -117.96              0.27828              
 -118.                0.27901              
 -118.04              0.28014              
 -118.08              0.27708              
 -118.12              0.27373              
 -118.16              0.27500              
 -118.2               0.28019              
 -118.24              0.27825              
 -118.28              0.26511              
 -118.32              0.25481              
 -118.36              0.24895              
 -118.4               0.24827              
 -118.44              0.24915              
 -118.48              0.24324              
 -118.52              0.23331              
 -118.56              0.22529              
 -118.6               0.21798              
 -118.64              0.21033              
 -118.68              0.20717              
 -118.72              0.20833              
 -118.76              0.20854              
 -118.8               0.20482              
 -118.84              0.20180              
 -118.88              0.19760              
 -118.92              0.19814              
 -118.96              0.20373              
 -119.                0.20676              
 -119.04              0.20514              
 -119.08              0.19542              
 -119.12              0.18310              
 -119.16              0.17534              
 -119.2               0.16787              
 -119.24              0.16961              
 -119.28              0.17927              
 -119.32              0.18956              
 -119.36              0.20294              
 -119.4               0.20994              
 -119.44              0.21684              
 -119.48              0.21408              
 -119.52              0.20146              
 -119.56              0.18966              
 -119.6               0.18274              
 -119.64              0.18229              
 -119.68              0.18715              
 -119.72              0.19652              
 -119.76              0.20168              
 -119.8               0.20164              
 -119.84              0.18742              
 -119.88              0.16846              
 -119.92              0.15874              
 -119.96              0.15273              
 -120.                0.15177              
 -120.04              0.15316              
 -120.08              0.15386              
 -120.12              0.15204              
 -120.16              0.14864              
 -120.2               0.14925              
 -120.24              0.14664              
 -120.28              0.13503              
 -120.32              0.12353              
 -120.36              0.11681              
 -120.4               0.11371              
 -120.44              0.11121              
 -120.48              0.11445              
 -120.52              0.11837              
 -120.56              0.11827              
 -120.6               0.11669              
 -120.64              0.10879              
 -120.68              0.10009              
 -120.72              0.09242              
 -120.76              0.08836              
 -120.8               0.09739              
 -120.84              0.10697              
 -120.88              0.11628              
 -120.92              0.12062              
 -120.96              0.12140              
 -121.                0.12264              
 -121.04              0.12291              
 -121.08              0.11681              
 -121.12              0.10917              
 -121.16              0.10505              
 -121.2               0.10110              
 -121.24              0.10064              
 -121.28              0.10597              
 -121.32              0.10733              
 -121.36              0.10831              
 -121.4               0.10053              
 -121.44              0.09430              
 -121.48              0.09586              
 -121.52              0.09756              
 -121.56              0.10508              
 -121.6               0.11357              
 -121.64              0.11613              
 -121.68              0.11721              
 -121.72              0.12148              
 -121.76              0.12646              
 -121.8               0.13164              
 -121.84              0.13715              
 -121.88              0.13844              
 -121.92              0.13955              
 -121.96              0.14064              
 -122.                0.14175              
 -122.04              0.14286              
 -122.08              0.14397              
 -122.12              0.14475              
 -122.16              0.13710              
 -122.2               0.12490              
 -122.24              0.11243              
 -122.28              0.10079              
 -122.32              0.09216              
 -122.36              0.09169              
 -122.4               0.10486              
 -122.44              0.11460              
 -122.48              0.12484              
 -122.52              0.14299              
 -122.56              0.15585              
 -122.6               0.16359              
 -122.64              0.16078              
 -122.68              0.15385              
 -122.72              0.14412              
 -122.76              0.13245              
 -122.8               0.13428              
 -122.84              0.15022              
 -122.88              0.16815              
 -122.92              0.18615              
 -122.96              0.19653              
 -123.                0.18041              
 -123.04              0.16086              
 -123.08              0.14448              
 -123.12              0.12475              
 -123.16              0.12016              
 -123.2               0.13364              
 -123.24              0.14417              
 -123.28              0.14915              
 -123.32              0.14982              
 -123.36              0.14895              
 -123.4               0.14962              
 -123.44              0.15102              
 -123.48              0.15191              
 -123.52              0.16142              
 -123.56              0.17053              
 -123.6               0.17133              
 -123.64              0.17214              
 -123.68              0.16709              
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##END=
