##TITLE=              31P MAS NMR spectrum of as-made VPI-5 (hydrated)
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             Grobet et al. Applied Catalysis, 56, L21-L27 (1989) Figure 1
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University
##LONG DATE=          2020/07/22 14:23:49
##SOURCE REFERENCE=   VFI-31P-Grobet-1989-asmade
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              VFI
##NAMES=              VPI-5
##SAMPLE DESCRIPTION= VPI-5, as-made, hydrated

$$Bibliographic information 
##$AUTHORS=           Grobet, P.J., Martens, J.A., Balakrishnan, I., Mertens, M., Jacobs, P.A.
##$TITLE=             The very large pore molecular sieve VPI-5: An aluminophosphate-hydrate
##$JOURNAL=           Applied Catalysis
##$VOLUME=            56
##$PAGES=             L21-L27
##$YEAR=              1989
##$DOI=               10.1016/S0166-9834(00)80152-9
##$FIGURE=            Figure 1

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         3
##$PEAK LABELS=        P1         P2         P3        
##$PEAK TSITES=        T2         T1         T1        
##$PEAK POSITIONS=    -32.9677   -27.2259   -23.5956   
##$PEAK AREAS=         1.         1.         1.        
##$PEAK WIDTHS=        1.70235    1.544      1.8101    
##$PEAK SHAPES=        0.31851    0.31851    0.31851   
##$NUMBERING REF=     McCusker et al. Zeolites, 11, 308-313 (1991)
##$ASSIGN REF=        Engelhardt and Veeman. J. Chem. Soc., Chem. Commun., 622-623 (1993) Table 1
##$ASSIGN METHOD=     2D correlation NMR
##$COMMENT=           Peak assignments based on the 2D 27Al/31P correlation spectrum in van Eck and Veeman, JACS 115, 1168-1169 (1993) Figure 3

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^31P
##.OBSERVE FREQUENCY= 162
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     5000

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=             -6.1                  
##LASTX=              -42.7                 
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            367
##FIRSTY=              0.00369              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
 -6.1                 0.00369              
 -6.2                 0.00348              
 -6.3                 0.00342              
 -6.4                 0.00359              
 -6.5                 0.00396              
 -6.6                 0.00420              
 -6.7                 0.00440              
 -6.8                 0.00460              
 -6.9                 0.00473              
 -7.                  0.00426              
 -7.1                 0.00357              
 -7.2                 0.00269              
 -7.3                 0.00250              
 -7.4                 0.00293              
 -7.5                 0.00332              
 -7.6                 0.00372              
 -7.7                 0.00371              
 -7.8                 0.00346              
 -7.9                 0.00344              
 -8.                  0.00345              
 -8.1                 0.00356              
 -8.2                 0.00417              
 -8.3                 0.00463              
 -8.4                 0.00449              
 -8.5                 0.00367              
 -8.6                 0.00361              
 -8.7                 0.00414              
 -8.8                 0.00445              
 -8.9                 0.00446              
 -9.                  0.00392              
 -9.1                 0.00346              
 -9.2                 0.00344              
 -9.3                 0.00345              
 -9.4                 0.00343              
 -9.5                 0.00378              
 -9.6                 0.00455              
 -9.7                 0.00473              
 -9.8                 0.00454              
 -9.9                 0.00414              
 -10.                 0.00413              
 -10.1                0.00440              
 -10.2                0.00463              
 -10.3                0.00449              
 -10.4                0.00399              
 -10.5                0.00368              
 -10.6                0.00363              
 -10.7                0.00444              
 -10.8                0.00522              
 -10.9                0.00549              
 -11.                 0.00564              
 -11.1                0.00522              
 -11.2                0.00474              
 -11.3                0.00393              
 -11.4                0.00349              
 -11.5                0.00332              
 -11.6                0.00293              
 -11.7                0.00279              
 -11.8                0.00293              
 -11.9                0.00332              
 -12.                 0.00345              
 -12.1                0.00357              
 -12.2                0.00381              
 -12.3                0.00406              
 -12.4                0.00385              
 -12.5                0.00337              
 -12.6                0.00292              
 -12.7                0.00302              
 -12.8                0.00368              
 -12.9                0.00407              
 -13.                 0.00384              
 -13.1                0.00354              
 -13.2                0.00339              
 -13.3                0.00384              
 -13.4                0.00446              
 -13.5                0.00473              
 -13.6                0.00450              
 -13.7                0.00412              
 -13.8                0.00402              
 -13.9                0.00435              
 -14.                 0.00511              
 -14.1                0.00546              
 -14.2                0.00562              
 -14.3                0.00585              
 -14.4                0.00591              
 -14.5                0.00587              
 -14.6                0.00622              
 -14.7                0.00697              
 -14.8                0.00731              
 -14.9                0.00725              
 -15.                 0.00647              
 -15.1                0.00595              
 -15.2                0.00589              
 -15.3                0.00592              
 -15.4                0.00571              
 -15.5                0.00522              
 -15.6                0.00492              
 -15.7                0.00455              
 -15.8                0.00390              
 -15.9                0.00349              
 -16.                 0.00328              
 -16.1                0.00285              
 -16.2                0.00310              
 -16.3                0.00358              
 -16.4                0.00421              
 -16.5                0.00462              
 -16.6                0.00468              
 -16.7                0.00467              
 -16.8                0.00467              
 -16.9                0.00474              
 -17.                 0.00531              
 -17.1                0.00586              
 -17.2                0.00590              
 -17.3                0.00591              
 -17.4                0.00583              
 -17.5                0.00633              
 -17.6                0.00732              
 -17.7                0.00897              
 -17.8                0.01016              
 -17.9                0.01007              
 -18.                 0.00966              
 -18.1                0.00890              
 -18.2                0.00803              
 -18.3                0.00740              
 -18.4                0.00717              
 -18.5                0.00711              
 -18.6                0.00714              
 -18.7                0.00708              
 -18.8                0.00737              
 -18.9                0.00729              
 -19                  0.00654              
 -19.1                0.00527              
 -19.2                0.00480              
 -19.3                0.00503              
 -19.4                0.00508              
 -19.5                0.00451              
 -19.6                0.00411              
 -19.7                0.00418              
 -19.8                0.00502              
 -19.9                0.00588              
 -20.                 0.00626              
 -20.1                0.00648              
 -20.2                0.00628              
 -20.3                0.00595              
 -20.4                0.00603              
 -20.5                0.00711              
 -20.6                0.00842              
 -20.7                0.00896              
 -20.8                0.00912              
 -20.9                0.00969              
 -21.                 0.01026              
 -21.1                0.01078              
 -21.2                0.01213              
 -21.3                0.01450              
 -21.4                0.01727              
 -21.5                0.02078              
 -21.6                0.02419              
 -21.7                0.02706              
 -21.8                0.03250              
 -21.9                0.03995              
 -22.                 0.05131              
 -22.1                0.06327              
 -22.2                0.07920              
 -22.3                0.09785              
 -22.4                0.11654              
 -22.5                0.13827              
 -22.6                0.17322              
 -22.7                0.20997              
 -22.8                0.25796              
 -22.9                0.30182              
 -23.                 0.34500              
 -23.1                0.38558              
 -23.2                0.42047              
 -23.3                0.44611              
 -23.4                0.45779              
 -23.5                0.46552              
 -23.6                0.46669              
 -23.7                0.45845              
 -23.8                0.44002              
 -23.9                0.41017              
 -24.                 0.37578              
 -24.1                0.34392              
 -24.2                0.31742              
 -24.3                0.28663              
 -24.4                0.25922              
 -24.5                0.22754              
 -24.6                0.19272              
 -24.7                0.16742              
 -24.8                0.14772              
 -24.9                0.12975              
 -25.                 0.11402              
 -25.1                0.10244              
 -25.2                0.09336              
 -25.3                0.08786              
 -25.4                0.08534              
 -25.5                0.08444              
 -25.6                0.08666              
 -25.7                0.09632              
 -25.8                0.10806              
 -25.9                0.12269              
 -26.                 0.14541              
 -26.1                0.17141              
 -26.2                0.21304              
 -26.3                0.24518              
 -26.4                0.29458              
 -26.5                0.34873              
 -26.6                0.40381              
 -26.7                0.45406              
 -26.8                0.48766              
 -26.9                0.52388              
 -27.                 0.55486              
 -27.1                0.56438              
 -27.2                0.56618              
 -27.3                0.55886              
 -27.4                0.53953              
 -27.5                0.51980              
 -27.6                0.49149              
 -27.7                0.44729              
 -27.8                0.40664              
 -27.9                0.35955              
 -28.                 0.31306              
 -28.1                0.27664              
 -28.2                0.24715              
 -28.3                0.21357              
 -28.4                0.17740              
 -28.5                0.15022              
 -28.6                0.12263              
 -28.7                0.10486              
 -28.8                0.08175              
 -28.9                0.06085              
 -29.                 0.04973              
 -29.1                0.04054              
 -29.2                0.03482              
 -29.3                0.03062              
 -29.4                0.02711              
 -29.5                0.02471              
 -29.6                0.02297              
 -29.7                0.02202              
 -29.8                0.02099              
 -29.9                0.02011              
 -30.                 0.01932              
 -30.1                0.01869              
 -30.2                0.01854              
 -30.3                0.01854              
 -30.4                0.01802              
 -30.5                0.01730              
 -30.6                0.01693              
 -30.7                0.01692              
 -30.8                0.01699              
 -30.9                0.01781              
 -31.                 0.01941              
 -31.1                0.02235              
 -31.2                0.02527              
 -31.3                0.03130              
 -31.4                0.04224              
 -31.5                0.05665              
 -31.6                0.06930              
 -31.7                0.08386              
 -31.8                0.11307              
 -31.9                0.14550              
 -32.                 0.18353              
 -32.1                0.22510              
 -32.2                0.27288              
 -32.3                0.31647              
 -32.4                0.35943              
 -32.5                0.40318              
 -32.6                0.43657              
 -32.7                0.46196              
 -32.8                0.48035              
 -32.9                0.48289              
 -33.                 0.48105              
 -33.1                0.47359              
 -33.2                0.44540              
 -33.3                0.41083              
 -33.4                0.37842              
 -33.5                0.34086              
 -33.6                0.31029              
 -33.7                0.28575              
 -33.8                0.2568               
 -33.9                0.21701              
 -34.                 0.18348              
 -34.1                0.15475              
 -34.2                0.12033              
 -34.3                0.09339              
 -34.4                0.07335              
 -34.5                0.05826              
 -34.6                0.04453              
 -34.7                0.03353              
 -34.8                0.02346              
 -34.9                0.01657              
 -35.                 0.01367              
 -35.1                0.01151              
 -35.2                0.00961              
 -35.3                0.00818              
 -35.4                0.00671              
 -35.5                0.00583              
 -35.6                0.00645              
 -35.7                0.00709              
 -35.8                0.00717              
 -35.9                0.00689              
 -36.                 0.00651              
 -36.1                0.00669              
 -36.2                0.00724              
 -36.3                0.00842              
 -36.4                0.00918              
 -36.5                0.00878              
 -36.6                0.00841              
 -36.7                0.00824              
 -36.8                0.00762              
 -36.9                0.00729              
 -37.                 0.00746              
 -37.1                0.00756              
 -37.2                0.00679              
 -37.3                0.00587              
 -37.4                0.00553              
 -37.5                0.00512              
 -37.6                0.00474              
 -37.7                0.00466              
 -37.8                0.00468              
 -37.9                0.00467              
 -38.                 0.00468              
 -38.1                0.00451              
 -38.2                0.00416              
 -38.3                0.00378              
 -38.4                0.00357              
 -38.5                0.00417              
 -38.6                0.00451              
 -38.7                0.00426              
 -38.8                0.00363              
 -38.9                0.00342              
 -39.                 0.00344              
 -39.1                0.00372              
 -39.2                0.00456              
 -39.3                0.00439              
 -39.4                0.00364              
 -39.5                0.00283              
 -39.6                0.00221              
 -39.7                0.00250              
 -39.8                0.00284              
 -39.9                0.00260              
 -40.                 0.00243              
 -40.1                0.00245              
 -40.2                0.00228              
 -40.3                0.00221              
 -40.4                0.00221              
 -40.5                0.00236              
 -40.6                0.00285              
 -40.7                0.00231              
 -40.8                0.00165              
 -40.9                0.00153              
 -41.                 0.00206              
 -41.1                0.00287              
 -41.2                0.00337              
 -41.3                0.00326              
 -41.4                0.00275              
 -41.5                0.00259              
 -41.6                0.00301              
 -41.7                0.00349              
 -41.8                0.00393              
 -41.9                0.00452              
 -42.                 0.00474              
 -42.1                0.00448              
 -42.2                0.00374              
 -42.3                0.00333              
 -42.4                0.00399              
 -42.5                0.00464              
 -42.6                0.00468              
 -42.7                0.00467              
##END=
