IZA-SC
Rules for Framework Type Code Assignment |
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The following is a set of rules to be applied
by the Structure Commission of the International Zeolite Asssociation
(IZA-SC) in assigning a three-letter code to a new framework type. The
materials of interest are generally defined as open 4-connected 3-dimensional
nets, which have the general (approximate) composition AB2,
where A is a tetrahedrally connected atom and B is any 2-connected atom,
which may or may not be shared, between two neighboring A atoms. Inclusion
of other microporous materials is left to the discretion of the IZA-SC,
depending on the interest of the molecular sieve science community at
large. RULES |
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(i) | The IZA-SC is the only body that can coordinate the assignment of a code to such frameworks. The framework types are idealized, with no reference to actual materials, symmetry, composition, etc. and, therefore, ONLY refer to the connectivity. | |
(ii) | The code for a 4-connected 3-dimensional framework type shall consist of three capital letters. Other frameworks of interest shall be indicated by a (-) in front of the code. | |
(iii) | The three letters of the code shall be mnemonic and must refer to an actual material (i.e. the type material). These materials are chosen to be: | |
- mineral names (rules of the International Mineralogical Association followed) | ||
- commonly accepted synthetic material types | ||
- in the absence of the above, the workers who first determined the structure have priority in assigning the name | ||
(iv) | No mnemonic code can be assigned without the
structure being determined with the following exception: For "polytypic" materials, codes can be assigned as useful. Such codes shall be marked with an asterisk. |
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(v) | Codes of framework types which turn out to be in error are discredited. Later use of the code is not permitted. | |
(vi) | For all cases where a decision of the Structure Commission is required, a two thirds majority vote of the full commission shall be required. Such votes are taken verbally at a meeting of the Structure Commission or are done in writing on the initiative of the Chairperson and Co-chairperson. All evidence substantiating a new framework type must accompany the ballot. The members are obliged to respond to this request within one month and the Chairperson and Co-chairperson will make all possible effort to solicit replies from all members. |