##TITLE=              29Si MAS NMR spectrum of calcined dealuminated ZSM-5 (room temperature monoclinic)
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             Fyfe et al. J. Am. Chem. Soc., 110, 3373-3380 (1988) Figure 2b
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University College
##LONG DATE=          2019/06/20 11:37:00
##SOURCE REFERENCE=   MFI-29Si-Fyfe-1988
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              MFI
##NAMES=              ZSM-5
##NAMES=              Silicalite-1
##SAMPLE DESCRIPTION= ZSM-5, dealuminated, monoclinic

$$Bibliographic information 
##$AUTHORS=           Fyfe, C.A., Strobl, H., Kokotailo, G.T., Kennedy, G.J., Barlow, G.E.
##$TITLE=             Ultra-high-resolution 29Si solid-state MAS NMR investigation of sorbate and temperature-induced changes in the lattice structure of zeolite ZSM-5
##$JOURNAL=           Journal of the American Chemical Society
##$VOLUME=            110
##$PAGES=             3373-3380
##$YEAR=              1988
##$DOI=               10.1021/ja00219a005
##$FIGURE=            Figure 2b

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         24
##$PEAK TSITES=        T8         T4         T2         T11        T11        T3         T5         T6         T6         T12        T4         T12        T3         T7         T8         T2         T1         T7         T9         T1         T10        T10        T5         T9        
##$PEAK LABELS=        Si8        Si16       Si14       Si11       Si23       Si15       Si17       Si6        Si18       Si12       Si4        Si24       Si3        Si19       Si20       Si2        Si1        Si7        Si9        Si13       Si22       Si10       Si5        Si21      
##$PEAK POSITIONS=    -116.974   -116.013   -115.86    -115.181   -114.843   -114.53    -114.322   -114.133   -114.      -113.936   -113.922   -113.871   -113.773   -113.569   -113.349   -113.282   -113.282   -113.245   -112.847   -112.723   -112.573   -112.067   -111.76    -109.873   
##$PEAK AREAS=         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.        
##$PEAK WIDTHS=        0.10126    0.11366    0.08929    0.11491    0.10839    0.10059    0.09257    0.09057    0.08143    0.08143    0.08143    0.08143    0.07474    0.07509    0.07527    0.11111    0.11111    0.11111    0.08257    0.0909     0.08267    0.09794    0.09921    0.10075   
##$PEAK SHAPES=        1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1         
##$NUMBERING REF=     van Koningsveld, Zeolites 10, 235-242 (1990)
##$ASSIGN REF=        Fyfe et al. J. Am. Chem. Soc. 112, 8812-8820 (1990) Figure 7
##$ASSIGN METHOD=     2D correlation NMR

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^29Si
##.OBSERVE FREQUENCY= 79.5
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=             -108.06               
##LASTX=              -117.945              
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            660
##FIRSTY=              0.20906              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
 -108.06              0.20906              
 -108.075             0.18324              
 -108.09              0.15585              
 -108.105             0.14618              
 -108.12              0.16911              
 -108.135             0.17979              
 -108.15              0.19052              
 -108.165             0.20754              
 -108.18              0.19676              
 -108.195             0.16696              
 -108.21              0.15743              
 -108.225             0.15717              
 -108.24              0.14337              
 -108.255             0.10641              
 -108.27              0.09052              
 -108.285             0.09302              
 -108.3               0.10676              
 -108.315             0.12805              
 -108.33              0.15942              
 -108.345             0.18690              
 -108.36              0.16974              
 -108.375             0.11187              
 -108.39              0.11801              
 -108.405             0.16898              
 -108.42              0.22620              
 -108.435             0.24195              
 -108.45              0.21054              
 -108.465             0.18776              
 -108.48              0.13870              
 -108.495             0.08915              
 -108.51              0.09145              
 -108.525             0.12597              
 -108.54              0.18624              
 -108.555             0.21658              
 -108.57              0.19574              
 -108.585             0.13761              
 -108.6               0.10764              
 -108.615             0.14490              
 -108.63              0.17101              
 -108.645             0.15467              
 -108.66              0.13539              
 -108.675             0.13527              
 -108.69              0.12578              
 -108.705             0.11339              
 -108.72              0.12028              
 -108.735             0.13030              
 -108.75              0.14842              
 -108.765             0.17157              
 -108.78              0.18867              
 -108.795             0.18909              
 -108.81              0.17925              
 -108.825             0.18610              
 -108.84              0.17527              
 -108.855             0.13241              
 -108.87              0.08246              
 -108.885             0.05702              
 -108.9               0.04760              
 -108.915             0.05866              
 -108.93              0.10148              
 -108.945             0.14786              
 -108.96              0.16797              
 -108.975             0.13737              
 -108.99              0.14039              
 -109.005             0.17014              
 -109.02              0.17923              
 -109.035             0.17978              
 -109.05              0.17817              
 -109.065             0.16439              
 -109.08              0.15600              
 -109.095             0.15079              
 -109.11              0.14173              
 -109.125             0.11498              
 -109.14              0.09332              
 -109.155             0.09202              
 -109.17              0.10237              
 -109.185             0.13203              
 -109.2               0.17002              
 -109.215             0.20141              
 -109.23              0.18149              
 -109.245             0.14397              
 -109.26              0.11176              
 -109.275             0.09922              
 -109.29              0.09298              
 -109.305             0.10323              
 -109.32              0.09876              
 -109.335             0.08210              
 -109.35              0.07729              
 -109.365             0.07679              
 -109.38              0.07928              
 -109.395             0.12096              
 -109.41              0.15947              
 -109.425             0.17911              
 -109.44              0.17944              
 -109.455             0.18837              
 -109.47              0.20142              
 -109.485             0.20769              
 -109.5               0.23562              
 -109.515             0.25615              
 -109.53              0.24532              
 -109.545             0.25540              
 -109.56              0.26809              
 -109.575             0.27424              
 -109.59              0.27457              
 -109.605             0.2795               
 -109.62              0.30446              
 -109.635             0.33051              
 -109.65              0.36967              
 -109.665             0.43395              
 -109.68              0.54835              
 -109.695             0.72138              
 -109.71              0.89885              
 -109.725             1.08215              
 -109.74              1.30741              
 -109.755             1.61745              
 -109.77              1.93958              
 -109.785             2.17764              
 -109.8               2.60954              
 -109.815             3.17332              
 -109.83              3.78803              
 -109.845             4.6432               
 -109.86              5.76129              
 -109.875             6.61622              
 -109.89              6.13589              
 -109.905             4.79441              
 -109.92              3.50064              
 -109.935             2.50795              
 -109.95              1.99505              
 -109.965             1.61968              
 -109.98              1.30349              
 -109.995             1.00131              
 -110.01              0.74145              
 -110.025             0.54273              
 -110.04              0.43193              
 -110.055             0.33379              
 -110.07              0.28614              
 -110.085             0.27434              
 -110.1               0.24524              
 -110.115             0.20491              
 -110.13              0.15593              
 -110.145             0.10249              
 -110.16              0.02353              
 -110.175             0.00104              
 -110.19              0.08884              
 -110.205             0.13292              
 -110.22              0.14261              
 -110.235             0.13534              
 -110.25              0.12145              
 -110.265             0.13006              
 -110.28              0.13515              
 -110.295             0.12156              
 -110.31              0.12370              
 -110.325             0.13541              
 -110.34              0.12116              
 -110.355             0.07963              
 -110.37              0.03323              
 -110.385             0.03361              
 -110.4               0.05029              
 -110.415             0.05522              
 -110.43              0.05637              
 -110.445             0.08050              
 -110.46              0.05444              
 -110.475            -0.00923              
 -110.49             -0.03988              
 -110.505             0.01912              
 -110.52              0.06657              
 -110.535             0.09220              
 -110.55              0.09206              
 -110.565             0.07115              
 -110.58              0.03402              
 -110.595             0.01162              
 -110.61              0.00588              
 -110.625             0.01507              
 -110.64              0.00343              
 -110.655            -0.03346              
 -110.67             -0.05946              
 -110.685            -0.02893              
 -110.7               0.03471              
 -110.715             0.04869              
 -110.73              0.03033              
 -110.745             0.00400              
 -110.76              0.01618              
 -110.775             0.03429              
 -110.79              0.03668              
 -110.805             0.03287              
 -110.82              0.06136              
 -110.835             0.07991              
 -110.85              0.04865              
 -110.865             0.04275              
 -110.88              0.06178              
 -110.895             0.09214              
 -110.91              0.09949              
 -110.925             0.05681              
 -110.94              0.00229              
 -110.955            -0.01795              
 -110.97             -0.00040              
 -110.985             0.03654              
 -111.                0.05890              
 -111.015             0.01629              
 -111.03              0.00618              
 -111.045             0.02636              
 -111.06              0.03941              
 -111.075             0.06743              
 -111.09              0.09275              
 -111.105             0.09879              
 -111.12              0.10834              
 -111.135             0.11325              
 -111.15              0.09873              
 -111.165             0.06676              
 -111.18              0.06724              
 -111.195             0.10010              
 -111.21              0.12282              
 -111.225             0.15295              
 -111.24              0.18174              
 -111.255             0.20138              
 -111.27              0.16298              
 -111.285             0.12512              
 -111.3               0.10215              
 -111.315             0.09190              
 -111.33              0.09171              
 -111.345             0.09159              
 -111.36              0.09160              
 -111.375             0.09162              
 -111.39              0.09157              
 -111.405             0.09160              
 -111.42              0.10376              
 -111.435             0.12793              
 -111.45              0.14313              
 -111.465             0.16734              
 -111.48              0.20955              
 -111.495             0.23847              
 -111.51              0.2552               
 -111.525             0.29170              
 -111.54              0.33005              
 -111.555             0.38866              
 -111.57              0.47155              
 -111.585             0.60712              
 -111.6               0.79154              
 -111.615             0.92508              
 -111.63              1.19648              
 -111.645             1.56855              
 -111.66              1.95891              
 -111.675             2.31131              
 -111.69              2.72751              
 -111.705             3.32642              
 -111.72              3.96855              
 -111.735             4.83355              
 -111.75              5.93048              
 -111.765             6.96763              
 -111.78              6.2641               
 -111.795             4.58711              
 -111.81              3.07422              
 -111.825             2.47191              
 -111.84              1.98072              
 -111.855             1.74352              
 -111.87              1.45042              
 -111.885             1.19662              
 -111.9               1.10224              
 -111.915             1.24133              
 -111.93              1.4226               
 -111.945             1.60067              
 -111.96              1.81445              
 -111.975             2.0288               
 -111.99              2.29042              
 -112.005             2.72612              
 -112.02              3.48852              
 -112.035             4.45734              
 -112.05              5.51058              
 -112.065             6.81518              
 -112.08              6.2594               
 -112.095             5.56518              
 -112.11              3.68115              
 -112.125             2.31847              
 -112.14              1.82737              
 -112.155             1.44872              
 -112.17              1.11266              
 -112.185             0.87677              
 -112.2               0.71873              
 -112.215             0.54372              
 -112.23              0.43509              
 -112.245             0.34666              
 -112.26              0.28751              
 -112.275             0.26741              
 -112.29              0.26680              
 -112.305             0.25879              
 -112.32              0.26679              
 -112.335             0.31928              
 -112.35              0.38515              
 -112.365             0.45591              
 -112.38              0.52472              
 -112.395             0.64383              
 -112.41              0.77303              
 -112.425             0.95578              
 -112.44              1.20893              
 -112.455             1.50521              
 -112.47              1.83451              
 -112.485             2.19048              
 -112.5               2.72285              
 -112.515             3.42148              
 -112.53              4.38662              
 -112.545             5.7142               
 -112.56              7.19549              
 -112.585             8.35441              
 -112.59              7.8105               
 -112.605             6.17936              
 -112.62              3.965                
 -112.635             3.91741              
 -112.65              4.17182              
 -112.665             4.54693              
 -112.68              5.18596              
 -112.695             6.20558              
 -112.71              7.31819              
 -112.725             8.47352              
 -112.74              7.99252              
 -112.755             6.56589              
 -112.77              5.00691              
 -112.785             4.63941              
 -112.8               5.25007              
 -112.815             6.32976              
 -112.83              7.53875              
 -112.845             8.88255              
 -112.86              8.27316              
 -112.875             6.31467              
 -112.89              3.78051              
 -112.905             2.61635              
 -112.92              2.2038               
 -112.935             1.919                
 -112.95              1.70584              
 -112.965             1.48947              
 -112.98              1.26767              
 -112.995             1.18915              
 -113.01              1.21659              
 -113.025             1.2696               
 -113.04              1.36166              
 -113.055             1.60048              
 -113.07              1.82983              
 -113.085             2.10681              
 -113.1               2.61198              
 -113.115             3.1702               
 -113.13              3.81894              
 -113.145             4.46262              
 -113.16              5.19284              
 -113.175             6.15485              
 -113.19              7.30433              
 -113.205             8.50094              
 -113.22              10.2849              
 -113.235             12.8995              
 -113.25              15.353               
 -113.265             17.5799              
 -113.28              18.2952              
 -113.295             17.832               
 -113.31              16.3704              
 -113.325             14.3415              
 -113.35              15.3369              
 -113.355             13.9167              
 -113.37              11.8002              
 -113.385             7.89421              
 -113.4               5.53989              
 -113.415             4.8271               
 -113.43              4.09473              
 -113.445             3.83708              
 -113.46              3.67146              
 -113.475             3.58459              
 -113.49              3.86374              
 -113.505             4.40581              
 -113.52              5.19248              
 -113.535             6.47043              
 -113.55              8.32706              
 -113.565             9.91092              
 -113.58              9.70176              
 -113.595             7.67361              
 -113.61              4.95583              
 -113.625             3.61316              
 -113.64              3.43357              
 -113.655             3.51667              
 -113.67              3.74554              
 -113.685             4.04582              
 -113.7               4.60376              
 -113.715             5.6827               
 -113.73              7.11477              
 -113.745             8.75576              
 -113.76              10.2843              
 -113.775             11.8268              
 -113.79              11.2721              
 -113.805             10.6809              
 -113.82              10.1567              
 -113.835             10.5856              
 -113.85              12.1638              
 -113.865             14.3276              
 -113.88              16.0168              
 -113.895             17.9391              
 -113.91              20.1893              
 -113.925             21.1209              
 -113.94              19.8285              
 -113.955             17.1403              
 -113.97              15.1502              
 -113.995             16.4813              
 -114.                13.47                
 -114.015             11.9788              
 -114.03              10.3358              
 -114.045             7.72959              
 -114.06              6.67563              
 -114.075             6.64308              
 -114.09              7.07317              
 -114.105             7.99621              
 -114.12              9.06406              
 -114.135             9.67233              
 -114.15              8.25408              
 -114.165             6.91129              
 -114.18              5.47542              
 -114.195             4.37489              
 -114.21              4.19251              
 -114.225             4.20525              
 -114.24              4.26058              
 -114.255             4.61146              
 -114.27              5.25403              
 -114.285             6.1368               
 -114.3               7.02684              
 -114.315             7.94898              
 -114.33              8.55427              
 -114.345             7.37247              
 -114.36              5.3327               
 -114.375             4.27402              
 -114.39              3.87804              
 -114.405             3.56841              
 -114.42              3.51184              
 -114.435             3.64651              
 -114.45              3.89643              
 -114.465             4.2358               
 -114.48              4.72322              
 -114.495             5.38054              
 -114.51              6.26711              
 -114.525             7.03726              
 -114.54              7.4976               
 -114.555             6.39488              
 -114.57              5.03917              
 -114.585             3.6916               
 -114.6               2.94423              
 -114.615             2.57903              
 -114.63              2.35612              
 -114.645             2.17668              
 -114.66              1.96514              
 -114.675             1.83834              
 -114.69              1.78732              
 -114.705             1.76956              
 -114.72              1.91843              
 -114.735             2.11915              
 -114.75              2.40377              
 -114.765             2.75241              
 -114.78              3.04269              
 -114.795             3.49999              
 -114.81              4.2845               
 -114.825             5.38067              
 -114.84              6.74713              
 -114.855             6.2584               
 -114.87              5.44006              
 -114.885             3.98709              
 -114.9               2.73293              
 -114.915             2.17476              
 -114.93              1.82274              
 -114.945             1.63017              
 -114.96              1.44768              
 -114.975             1.27889              
 -114.99              1.17423              
 -115.005             1.09727              
 -115.02              1.09838              
 -115.035             1.14637              
 -115.05              1.2895               
 -115.065             1.60818              
 -115.08              1.86329              
 -115.095             2.1628               
 -115.11              2.55991              
 -115.125             3.03735              
 -115.14              3.60692              
 -115.155             4.29807              
 -115.17              5.47803              
 -115.185             6.22637              
 -115.2               5.61362              
 -115.215             3.76619              
 -115.23              2.74941              
 -115.245             2.29784              
 -115.26              1.81552              
 -115.275             1.61826              
 -115.29              1.37999              
 -115.305             1.09493              
 -115.32              0.84724              
 -115.335             0.69211              
 -115.35              0.60516              
 -115.365             0.52031              
 -115.38              0.48373              
 -115.395             0.47939              
 -115.41              0.46214              
 -115.425             0.41221              
 -115.44              0.34148              
 -115.455             0.29395              
 -115.47              0.28885              
 -115.485             0.32208              
 -115.5               0.3307               
 -115.515             0.30979              
 -115.53              0.29602              
 -115.545             0.32379              
 -115.56              0.34415              
 -115.575             0.34003              
 -115.59              0.34928              
 -115.605             0.37051              
 -115.62              0.41371              
 -115.635             0.45937              
 -115.65              0.54353              
 -115.665             0.63556              
 -115.68              0.72067              
 -115.695             0.88958              
 -115.71              1.14862              
 -115.725             1.48101              
 -115.74              1.80093              
 -115.755             2.10027              
 -115.77              2.44059              
 -115.785             2.88754              
 -115.8               3.57748              
 -115.815             4.55354              
 -115.83              5.68684              
 -115.845             7.07566              
 -115.86              8.08732              
 -115.875             7.58202              
 -115.89              6.5081               
 -115.905             5.1924               
 -115.92              4.4264               
 -115.935             4.20381              
 -115.95              4.35099              
 -115.965             4.66115              
 -115.98              5.09431              
 -115.995             5.7468               
 -116.01              6.29396              
 -116.025             6.61344              
 -116.04              5.30326              
 -116.055             3.99954              
 -116.07              2.90545              
 -116.085             2.56663              
 -116.1               2.23855              
 -116.115             1.90053              
 -116.13              1.71982              
 -116.145             1.51515              
 -116.16              1.28626              
 -116.175             1.07785              
 -116.19              0.89068              
 -116.205             0.78681              
 -116.22              0.73837              
 -116.235             0.69500              
 -116.25              0.67075              
 -116.265             0.64265              
 -116.28              0.59421              
 -116.295             0.52158              
 -116.31              0.39739              
 -116.325             0.26026              
 -116.34              0.20945              
 -116.355             0.21791              
 -116.37              0.25607              
 -116.385             0.21588              
 -116.4               0.16039              
 -116.415             0.15294              
 -116.43              0.23458              
 -116.445             0.26802              
 -116.46              0.26720              
 -116.475             0.26687              
 -116.49              0.25664              
 -116.505             0.22051              
 -116.52              0.18271              
 -116.535             0.14580              
 -116.55              0.11549              
 -116.565             0.09716              
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##END=
