##TITLE=              29Si MAS NMR spectrum of dealuminated ZSM-5 with p-xylene (8 mol/uc)
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             Fyfe et al. J. Am. Chem. Soc., 112, 8812-8820 (1990) Figure 2d
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University College
##LONG DATE=          2019/08/08 15:13:01
##SOURCE REFERENCE=   MFI-29Si-Fyfe-1990-pxy8
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              MFI
##NAMES=              ZSM-5
##NAMES=              Silicalite
##NAMES=              p-xylene
##SAMPLE DESCRIPTION= ZSM-5, p-xylene (8 mol/uc)
##TEMPERATURE=        293 K

$$Bibliographic information 
##$AUTHORS=           Fyfe, C.A., Grondey, H., Feng, Y., Kokotailo, G.T.
##$TITLE=             Natural-Abundance Two-Dimensional 29Si MAS NMR Investigation of the Three-Dimensional Bonding Connectivities in the Zeolite Catalyst ZSM-5
##$JOURNAL=           Journal of the American Chemical Society
##$VOLUME=            112
##$PAGES=             8812-8820
##$YEAR=              1990
##$DOI=               10.1021/ja00180a024
##$FIGURE=            Figure 2d

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         24
##$PEAK LABELS=        Si18       Si4        Si3        Si16       Si17       Si12       Si23       Si24       Si6        Si8        Si11       Si2        Si14       Si13       Si5        Si15       Si20       Si7        Si21       Si22       Si9        Si19       Si1        Si10      
##$PEAK TSITES=        T6         T4         T3         T4         T5         T12        T11        T12        T6         T8         T11        T2         T2         T1         T5         T3         T8         T7         T9         T10        T9         T7         T1         T10       
##$PEAK POSITIONS=    -119.562   -119.376   -118.57    -117.258   -116.91    -116.314   -115.484   -115.484   -115.484   -115.283   -115.041   -114.97    -114.622   -114.622   -114.438   -114.047   -113.962   -113.735   -113.245   -113.135   -112.804   -112.633   -111.575   -111.263   
##$PEAK AREAS=         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.        
##$PEAK WIDTHS=        0.13326    0.17998    0.16221    0.17789    0.14548    0.16107    0.1888     0.1888     0.1888     0.1888     0.21626    0.21626    0.17749    0.17749    0.17749    0.19197    0.19197    0.19197    0.14057    0.14057    0.15315    0.15315    0.16012    0.20132   
##$PEAK SHAPES=        1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1          1         
##$NUMBERING REF=     Van Koningsveld, Acta Cryst B45, 423-431 (1989)
##$ASSIGN REF=        Fyfe et al J. Am. Chem. Soc., 112, 8812-8820 (1990) Figure 9
##$ASSIGN METHOD=     2D correlation NMR
##$COMMENT=           

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^29Si
##.OBSERVE FREQUENCY= 79.5
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=             -108.04               
##LASTX=              -121.98               
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            698
##FIRSTY=              0.10340              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
 -108.04              0.10340              
 -108.06              0.14675              
 -108.08              0.19974              
 -108.1               0.23960              
 -108.12              0.2433               
 -108.14              0.20803              
 -108.16              0.16467              
 -108.18              0.15600              
 -108.2               0.16620              
 -108.22              0.18515              
 -108.24              0.20453              
 -108.26              0.19659              
 -108.28              0.15139              
 -108.3               0.10682              
 -108.32              0.09500              
 -108.34              0.10902              
 -108.36              0.12664              
 -108.38              0.12796              
 -108.4               0.10833              
 -108.42              0.08161              
 -108.44              0.06206              
 -108.46              0.06019              
 -108.48              0.07618              
 -108.5               0.10785              
 -108.52              0.12034              
 -108.54              0.10989              
 -108.56              0.11116              
 -108.58              0.15035              
 -108.6               0.20825              
 -108.62              0.25379              
 -108.64              0.27200              
 -108.66              0.25184              
 -108.68              0.20723              
 -108.7               0.18468              
 -108.72              0.20386              
 -108.74              0.22734              
 -108.76              0.23138              
 -108.78              0.21362              
 -108.8               0.17609              
 -108.82              0.14492              
 -108.84              0.12039              
 -108.86              0.10206              
 -108.88              0.09613              
 -108.9               0.10376              
 -108.92              0.12262              
 -108.94              0.15002              
 -108.96              0.16458              
 -108.98              0.15560              
 -109.                0.14325              
 -109.02              0.13038              
 -109.04              0.10508              
 -109.06              0.07533              
 -109.08              0.08214              
 -109.1               0.12411              
 -109.12              0.16590              
 -109.14              0.17192              
 -109.16              0.14704              
 -109.18              0.12627              
 -109.2               0.12701              
 -109.22              0.14787              
 -109.24              0.16918              
 -109.26              0.18414              
 -109.28              0.19315              
 -109.3               0.18363              
 -109.32              0.17345              
 -109.34              0.20605              
 -109.36              0.26390              
 -109.38              0.28755              
 -109.4               0.26155              
 -109.42              0.21161              
 -109.44              0.17689              
 -109.46              0.16876              
 -109.48              0.17398              
 -109.5               0.17141              
 -109.52              0.15762              
 -109.54              0.15035              
 -109.56              0.16188              
 -109.58              0.1679               
 -109.6               0.13172              
 -109.62              0.06841              
 -109.64              0.03217              
 -109.66              0.05670              
 -109.68              0.12211              
 -109.7               0.17989              
 -109.72              0.18497              
 -109.74              0.16370              
 -109.76              0.14600              
 -109.78              0.11968              
 -109.8               0.09487              
 -109.82              0.09712              
 -109.84              0.11690              
 -109.86              0.12221              
 -109.88              0.11430              
 -109.9               0.09986              
 -109.92              0.07165              
 -109.94              0.03590              
 -109.96              0.02582              
 -109.98              0.07033              
 -110.                0.12645              
 -110.02              0.15855              
 -110.04              0.16441              
 -110.06              0.15135              
 -110.08              0.13764              
 -110.1               0.13263              
 -110.12              0.13037              
 -110.14              0.12406              
 -110.16              0.12052              
 -110.18              0.12057              
 -110.2               0.12322              
 -110.22              0.13128              
 -110.24              0.13026              
 -110.26              0.10913              
 -110.28              0.07982              
 -110.3               0.04882              
 -110.32              0.03997              
 -110.34              0.05776              
 -110.36              0.08102              
 -110.38              0.08758              
 -110.4               0.07625              
 -110.42              0.04766              
 -110.44              0.01482              
 -110.46              0.00206              
 -110.48              0.03823              
 -110.5               0.11380              
 -110.52              0.16249              
 -110.54              0.15447              
 -110.56              0.11335              
 -110.58              0.06506              
 -110.6               0.05549              
 -110.62              0.07676              
 -110.64              0.07026              
 -110.66              0.02111              
 -110.68             -0.01219              
 -110.7              -0.00999              
 -110.72              0.00771              
 -110.74              0.03449              
 -110.76              0.07924              
 -110.78              0.10891              
 -110.8               0.10593              
 -110.82              0.07463              
 -110.84              0.04000              
 -110.86              0.03125              
 -110.88              0.03462              
 -110.9               0.05037              
 -110.92              0.07851              
 -110.94              0.09138              
 -110.96              0.07443              
 -110.98              0.06625              
 -111.                0.12784              
 -111.02              0.22229              
 -111.04              0.30955              
 -111.06              0.41267              
 -111.08              0.5546               
 -111.1               0.71252              
 -111.12              0.88188              
 -111.14              1.18351              
 -111.16              1.62178              
 -111.18              2.04414              
 -111.2               2.50114              
 -111.22              2.96492              
 -111.24              3.28718              
 -111.26              3.40989              
 -111.28              3.29955              
 -111.3               2.92416              
 -111.32              2.53232              
 -111.34              2.20443              
 -111.36              1.94901              
 -111.38              1.80026              
 -111.4               1.74514              
 -111.42              1.75894              
 -111.44              1.89398              
 -111.46              2.12982              
 -111.48              2.4452               
 -111.5               2.86335              
 -111.52              3.35428              
 -111.54              3.83294              
 -111.56              4.22599              
 -111.58              4.2456               
 -111.6               3.90267              
 -111.62              3.3042               
 -111.64              2.71089              
 -111.66              2.24805              
 -111.68              1.87001              
 -111.7               1.56278              
 -111.72              1.31698              
 -111.74              1.14688              
 -111.76              1.00897              
 -111.78              0.91117              
 -111.8               0.84815              
 -111.82              0.77856              
 -111.84              0.70791              
 -111.86              0.66097              
 -111.88              0.63663              
 -111.9               0.60971              
 -111.92              0.57145              
 -111.94              0.51651              
 -111.96              0.45314              
 -111.98              0.39169              
 -112.                0.35900              
 -112.02              0.34038              
 -112.04              0.30883              
 -112.06              0.27956              
 -112.08              0.25036              
 -112.1               0.23039              
 -112.12              0.21528              
 -112.14              0.19790              
 -112.16              0.17628              
 -112.18              0.14844              
 -112.2               0.13573              
 -112.22              0.15821              
 -112.24              0.20051              
 -112.26              0.23754              
 -112.28              0.22496              
 -112.3               0.18574              
 -112.32              0.17182              
 -112.34              0.17835              
 -112.36              0.17672              
 -112.38              0.18323              
 -112.4               0.24251              
 -112.42              0.32656              
 -112.44              0.46112              
 -112.46              0.71031              
 -112.48              0.96292              
 -112.5               1.27596              
 -112.52              1.67186              
 -112.54              2.11533              
 -112.56              2.7606               
 -112.58              3.60783              
 -112.6               4.37927              
 -112.62              4.93109              
 -112.64              5.0614               
 -112.66              4.80143              
 -112.68              4.34966              
 -112.7               4.04101              
 -112.72              4.00475              
 -112.74              4.20299              
 -112.76              4.67229              
 -112.78              5.09899              
 -112.8               5.19581              
 -112.82              4.80267              
 -112.84              4.1996               
 -112.86              3.66145              
 -112.88              3.15873              
 -112.9               2.69452              
 -112.92              2.39471              
 -112.94              2.23148              
 -112.96              2.14896              
 -112.98              2.15872              
 -113.                2.33388              
 -113.02              2.63544              
 -113.04              3.03331              
 -113.06              3.48296              
 -113.08              4.15925              
 -113.1               5.11773              
 -113.12              5.95407              
 -113.14              6.4355               
 -113.16              6.52573              
 -113.18              6.38                 
 -113.2               6.28487              
 -113.22              6.34455              
 -113.24              6.30525              
 -113.26              5.8641               
 -113.28              5.03718              
 -113.3               4.1277               
 -113.32              3.40486              
 -113.34              2.88399              
 -113.36              2.4079               
 -113.38              1.9792               
 -113.4               1.68469              
 -113.42              1.50728              
 -113.44              1.41205              
 -113.46              1.32218              
 -113.48              1.24788              
 -113.5               1.21326              
 -113.52              1.21152              
 -113.54              1.25583              
 -113.56              1.35512              
 -113.58              1.49617              
 -113.6               1.74595              
 -113.62              2.16342              
 -113.64              2.52067              
 -113.66              2.92938              
 -113.68              3.56152              
 -113.7               4.24289              
 -113.72              4.92175              
 -113.74              5.34136              
 -113.76              5.15468              
 -113.78              4.68235              
 -113.8               4.19837              
 -113.82              3.78418              
 -113.84              3.61978              
 -113.86              3.65323              
 -113.88              3.76108              
 -113.9               4.10258              
 -113.92              4.51323              
 -113.94              5.01346              
 -113.96              5.61065              
 -113.98              6.04832              
 -114.                6.27921              
 -114.02              6.25658              
 -114.04              5.93617              
 -114.06              5.41036              
 -114.08              4.81388              
 -114.1               4.13096              
 -114.12              3.49476              
 -114.14              3.00958              
 -114.16              2.62746              
 -114.18              2.41441              
 -114.2               2.31597              
 -114.22              2.26143              
 -114.24              2.29522              
 -114.26              2.40976              
 -114.28              2.5709               
 -114.3               2.74815              
 -114.32              2.98631              
 -114.34              3.32583              
 -114.36              3.74105              
 -114.38              4.21755              
 -114.4               4.72598              
 -114.42              5.16193              
 -114.44              5.40695              
 -114.46              5.46682              
 -114.48              5.51276              
 -114.5               5.62081              
 -114.52              5.85991              
 -114.54              6.34074              
 -114.56              7.0149               
 -114.58              7.83638              
 -114.6               8.48547              
 -114.62              8.67842              
 -114.64              8.37977              
 -114.66              7.61495              
 -114.68              6.48342              
 -114.7               5.50774              
 -114.72              4.72272              
 -114.74              4.17228              
 -114.76              3.83648              
 -114.78              3.59105              
 -114.8               3.43788              
 -114.82              3.42662              
 -114.84              3.50291              
 -114.86              3.73013              
 -114.88              4.08764              
 -114.9               4.47398              
 -114.92              4.98447              
 -114.94              5.60054              
 -114.96              6.17162              
 -114.98              6.52763              
 -115.                6.60072              
 -115.02              6.49967              
 -115.04              6.2851               
 -115.06              6.0151               
 -115.08              5.64785              
 -115.1               5.23837              
 -115.12              4.85366              
 -115.14              4.62299              
 -115.16              4.54898              
 -115.18              4.62172              
 -115.2               4.842                
 -115.22              5.13807              
 -115.24              5.34746              
 -115.26              5.42321              
 -115.28              5.36187              
 -115.3               5.27035              
 -115.32              5.42019              
 -115.34              5.82881              
 -115.36              6.42139              
 -115.38              7.30664              
 -115.4               8.53961              
 -115.42              9.55013              
 -115.44              10.3486              
 -115.46              10.9522              
 -115.48              11.2213              
 -115.5               10.9541              
 -115.52              10.0815              
 -115.54              8.54165              
 -115.56              7.02987              
 -115.58              5.94156              
 -115.6               5.02948              
 -115.62              4.36548              
 -115.64              3.69867              
 -115.66              3.10091              
 -115.68              2.61469              
 -115.7               2.1981               
 -115.72              1.93235              
 -115.74              1.74251              
 -115.76              1.63074              
 -115.78              1.54095              
 -115.8               1.41343              
 -115.82              1.28346              
 -115.84              1.18176              
 -115.86              1.10836              
 -115.88              1.03224              
 -115.9               0.93500              
 -115.92              0.85451              
 -115.94              0.81867              
 -115.96              0.80782              
 -115.98              0.82545              
 -116.                0.85134              
 -116.02              0.85771              
 -116.04              0.85235              
 -116.06              0.87260              
 -116.08              0.94348              
 -116.1               1.04136              
 -116.12              1.14959              
 -116.14              1.31923              
 -116.16              1.5599               
 -116.18              1.81343              
 -116.2               2.07919              
 -116.22              2.35783              
 -116.24              2.74564              
 -116.26              3.26434              
 -116.28              3.81585              
 -116.3               4.22573              
 -116.32              4.40692              
 -116.34              4.18674              
 -116.36              3.53916              
 -116.38              2.8868               
 -116.4               2.38964              
 -116.42              1.98803              
 -116.44              1.71694              
 -116.46              1.53692              
 -116.48              1.32838              
 -116.5               1.17453              
 -116.52              1.05063              
 -116.54              0.95999              
 -116.56              0.90636              
 -116.58              0.87645              
 -116.6               0.86618              
 -116.62              0.85807              
 -116.64              0.84695              
 -116.66              0.85144              
 -116.68              0.88591              
 -116.7               0.99223              
 -116.72              1.14585              
 -116.74              1.32774              
 -116.76              1.53746              
 -116.78              1.83134              
 -116.8               2.19023              
 -116.82              2.53505              
 -116.84              2.98475              
 -116.86              3.61949              
 -116.88              4.18754              
 -116.9               4.65525              
 -116.92              4.8754               
 -116.94              4.56483              
 -116.96              3.8329               
 -116.98              3.10191              
 -117.                2.44847              
 -117.02              2.12083              
 -117.04              1.97433              
 -117.06              1.78755              
 -117.08              1.70127              
 -117.1               1.69195              
 -117.12              1.73772              
 -117.14              1.90509              
 -117.16              2.19007              
 -117.18              2.527                
 -117.2               2.88509              
 -117.22              3.31982              
 -117.24              3.72805              
 -117.26              4.04084              
 -117.28              3.94453              
 -117.3               3.48358              
 -117.32              2.77294              
 -117.34              2.06327              
 -117.36              1.63162              
 -117.38              1.40286              
 -117.4               1.21546              
 -117.42              1.04067              
 -117.44              0.90362              
 -117.46              0.80860              
 -117.48              0.71442              
 -117.5               0.62440              
 -117.52              0.56672              
 -117.54              0.52412              
 -117.56              0.48561              
 -117.58              0.46698              
 -117.6               0.47153              
 -117.62              0.49121              
 -117.64              0.48296              
 -117.66              0.44584              
 -117.68              0.39281              
 -117.7               0.34594              
 -117.72              0.32476              
 -117.74              0.32898              
 -117.76              0.33943              
 -117.78              0.33174              
 -117.8               0.30028              
 -117.82              0.28005              
 -117.84              0.30160              
 -117.86              0.36113              
 -117.88              0.40645              
 -117.9               0.40077              
 -117.92              0.34562              
 -117.94              0.28565              
 -117.96              0.26016              
 -117.98              0.28360              
 -118.                0.31328              
 -118.02              0.31729              
 -118.04              0.32995              
 -118.06              0.36483              
 -118.08              0.39562              
 -118.1               0.40278              
 -118.12              0.37726              
 -118.14              0.35511              
 -118.16              0.38043              
 -118.18              0.41912              
 -118.2               0.43865              
 -118.22              0.45092              
 -118.24              0.48968              
 -118.26              0.54190              
 -118.28              0.57441              
 -118.3               0.62203              
 -118.32              0.67858              
 -118.34              0.73338              
 -118.36              0.81806              
 -118.38              0.98713              
 -118.4               1.2058               
 -118.42              1.44905              
 -118.44              1.71654              
 -118.46              1.97945              
 -118.48              2.31374              
 -118.5               2.69003              
 -118.52              3.10373              
 -118.54              3.56688              
 -118.56              3.97286              
 -118.58              4.16739              
 -118.6               3.947                
 -118.62              3.38829              
 -118.64              2.72918              
 -118.66              2.08964              
 -118.68              1.65224              
 -118.7               1.38872              
 -118.72              1.18922              
 -118.74              1.00196              
 -118.76              0.83562              
 -118.78              0.74445              
 -118.8               0.68105              
 -118.82              0.64381              
 -118.84              0.63013              
 -118.86              0.63036              
 -118.88              0.62282              
 -118.9               0.59020              
 -118.92              0.53784              
 -118.94              0.49242              
 -118.96              0.46863              
 -118.98              0.46258              
 -119.                0.47509              
 -119.02              0.50024              
 -119.04              0.51656              
 -119.06              0.56639              
 -119.08              0.63997              
 -119.1               0.69328              
 -119.12              0.73797              
 -119.14              0.80463              
 -119.16              0.90472              
 -119.18              1.02515              
 -119.2               1.24743              
 -119.22              1.53935              
 -119.24              1.84249              
 -119.26              2.13837              
 -119.28              2.39668              
 -119.3               2.65739              
 -119.32              3.03901              
 -119.34              3.46264              
 -119.36              3.85862              
 -119.38              4.21337              
 -119.4               4.2763               
 -119.42              4.07119              
 -119.44              3.8345               
 -119.46              3.7006               
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##END=
