##TITLE=              29Si MAS NMR spectrum of calcined dealuminated ZSM-23
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             Fyfe et al. Zeolites, 12, 50-53 (1992) Figure 3a
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University College
##LONG DATE=          2019/08/08 15:18:24
##SOURCE REFERENCE=   MTT-29Si-Fyfe-1992
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              MTT
##NAMES=              ZSM-23
##SAMPLE DESCRIPTION= ZSM-23, dealuminated

$$Bibliographic information 
##$AUTHORS=           Fyfe, C.A., Grondey, H., Feng, Y., Kokotailo, G.T., Ernst, S., Weitkamp, J.
##$TITLE=             Two-dimensional solid-state 29Si n.m.r. investigation of the three-dimensional bonding connectivities and structure of zeolite ZSM-23
##$JOURNAL=           Zeolites
##$VOLUME=            12
##$PAGES=             50-53
##$YEAR=              1992
##$DOI=               10.1016/0144-2449(92)90009-E
##$FIGURE=            Figure 3a

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         12
##$PEAK LABELS=        Si5        Si1        Si8        Si6        Si11       Si3        Si9        Si10       Si4        Si2        Si7        Si12      
##$PEAK TSITES=        T7         T1         T1         T4         T4         T3         T2         T3         T6         T2         T5         T5        
##$PEAK POSITIONS=    -114.427   -114.134   -114.134   -112.864   -112.102   -112.02    -111.744   -111.484   -110.508   -110.375   -109.957   -108.588   
##$PEAK AREAS=         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.         1.        
##$PEAK WIDTHS=        0.39011    0.32603    0.32603    0.44454    0.32684    0.32684    0.3466     0.35966    0.28055    0.28055    0.33563    0.39988   
##$PEAK SHAPES=        1          1          1          1          1          1          1          1          1          1          1          1         
##$NUMBERING REF=     Marler et al., J. Appl. Cryst., 26, 636-644 (1993)
##$ASSIGN REF=        Hochegrafe et al. Chem. Mater. 12, 336-342 (2000) Table 2
##$ASSIGN METHOD=     2D correlation NMR, average Si-Si distances
##$COMMENT=           

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^29Si
##.OBSERVE FREQUENCY= 79.5
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     3500

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=             -105.42               
##LASTX=              -117.46               
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            603
##FIRSTY=              0.12255              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
 -105.42              0.12255              
 -105.44              0.10944              
 -105.46              0.08739              
 -105.48              0.06756              
 -105.5               0.04843              
 -105.52              0.03285              
 -105.54              0.02320              
 -105.56              0.02174              
 -105.58              0.02205              
 -105.6               0.02665              
 -105.62              0.03119              
 -105.64              0.03266              
 -105.66              0.03551              
 -105.68              0.03879              
 -105.7               0.04015              
 -105.72              0.04756              
 -105.74              0.06072              
 -105.76              0.07110              
 -105.78              0.08694              
 -105.8               0.09870              
 -105.82              0.10427              
 -105.84              0.10255              
 -105.86              0.08917              
 -105.88              0.07518              
 -105.9               0.06669              
 -105.92              0.05979              
 -105.94              0.05626              
 -105.96              0.05547              
 -105.98              0.05555              
 -106.                0.06279              
 -106.02              0.07669              
 -106.04              0.08987              
 -106.06              0.10408              
 -106.08              0.10646              
 -106.1               0.09994              
 -106.12              0.09396              
 -106.14              0.07958              
 -106.16              0.05729              
 -106.18              0.04217              
 -106.2               0.03253              
 -106.22              0.02782              
 -106.24              0.03109              
 -106.26              0.04331              
 -106.28              0.06204              
 -106.3               0.07861              
 -106.32              0.08636              
 -106.34              0.08942              
 -106.36              0.08376              
 -106.38              0.06692              
 -106.4               0.04380              
 -106.42              0.02803              
 -106.44              0.02330              
 -106.46              0.03032              
 -106.48              0.04046              
 -106.5               0.04433              
 -106.52              0.05026              
 -106.54              0.05548              
 -106.56              0.05415              
 -106.58              0.04661              
 -106.6               0.03338              
 -106.62              0.02768              
 -106.64              0.03250              
 -106.66              0.03903              
 -106.68              0.05015              
 -106.7               0.06356              
 -106.72              0.06688              
 -106.74              0.06694              
 -106.76              0.06298              
 -106.78              0.05677              
 -106.8               0.05298              
 -106.82              0.05325              
 -106.84              0.06323              
 -106.86              0.07412              
 -106.88              0.08625              
 -106.9               0.09691              
 -106.92              0.10032              
 -106.94              0.09145              
 -106.96              0.07697              
 -106.98              0.06213              
 -107.                0.05095              
 -107.02              0.04427              
 -107.04              0.04415              
 -107.06              0.04434              
 -107.08              0.04429              
 -107.1               0.04436              
 -107.12              0.04432              
 -107.14              0.04580              
 -107.16              0.04773              
 -107.18              0.05130              
 -107.2               0.05683              
 -107.22              0.06654              
 -107.24              0.07290              
 -107.26              0.07589              
 -107.28              0.07605              
 -107.3               0.07068              
 -107.32              0.06697              
 -107.34              0.06745              
 -107.36              0.07812              
 -107.38              0.09507              
 -107.4               0.11156              
 -107.42              0.11978              
 -107.44              0.12253              
 -107.46              0.10897              
 -107.48              0.08791              
 -107.5               0.06634              
 -107.52              0.04873              
 -107.54              0.03569              
 -107.56              0.03630              
 -107.58              0.04177              
 -107.6               0.05791              
 -107.62              0.08343              
 -107.64              0.09786              
 -107.66              0.10324              
 -107.68              0.10930              
 -107.7               0.11577              
 -107.72              0.11967              
 -107.74              0.12579              
 -107.76              0.13126              
 -107.78              0.13568              
 -107.8               0.13920              
 -107.82              0.13842              
 -107.84              0.12902              
 -107.86              0.11944              
 -107.88              0.11421              
 -107.9               0.11390              
 -107.92              0.12734              
 -107.94              0.15265              
 -107.96              0.16947              
 -107.98              0.18640              
 -108.                0.19802              
 -108.02              0.20177              
 -108.04              0.19467              
 -108.06              0.17517              
 -108.08              0.15748              
 -108.1               0.14568              
 -108.12              0.14086              
 -108.14              0.13941              
 -108.16              0.15504              
 -108.18              0.18495              
 -108.2               0.21292              
 -108.22              0.25038              
 -108.24              0.30394              
 -108.26              0.35713              
 -108.28              0.40920              
 -108.3               0.47370              
 -108.32              0.55357              
 -108.34              0.62734              
 -108.36              0.70643              
 -108.38              0.80383              
 -108.4               0.90421              
 -108.42              1.01627              
 -108.44              1.14102              
 -108.46              1.3012               
 -108.48              1.42241              
 -108.5               1.52631              
 -108.52              1.6166               
 -108.54              1.68932              
 -108.56              1.72834              
 -108.58              1.68863              
 -108.6               1.61717              
 -108.62              1.54527              
 -108.64              1.45812              
 -108.66              1.36232              
 -108.68              1.26761              
 -108.7               1.19466              
 -108.72              1.12798              
 -108.74              1.05237              
 -108.76              0.99650              
 -108.78              0.93897              
 -108.8               0.89012              
 -108.82              0.85255              
 -108.84              0.81261              
 -108.86              0.77356              
 -108.88              0.74386              
 -108.9               0.70842              
 -108.92              0.67006              
 -108.94              0.63351              
 -108.96              0.58658              
 -108.98              0.53717              
 -109.                0.48994              
 -109.02              0.45258              
 -109.04              0.42674              
 -109.06              0.40393              
 -109.08              0.39588              
 -109.1               0.39286              
 -109.12              0.39440              
 -109.14              0.40057              
 -109.16              0.41052              
 -109.18              0.41787              
 -109.2               0.42448              
 -109.22              0.43296              
 -109.24              0.43414              
 -109.26              0.42164              
 -109.28              0.40796              
 -109.3               0.39479              
 -109.32              0.37863              
 -109.34              0.36692              
 -109.36              0.36044              
 -109.38              0.35875              
 -109.4               0.36505              
 -109.42              0.37428              
 -109.44              0.38279              
 -109.46              0.39449              
 -109.48              0.40836              
 -109.5               0.41543              
 -109.52              0.42560              
 -109.54              0.44302              
 -109.56              0.46626              
 -109.58              0.49569              
 -109.6               0.53835              
 -109.62              0.57572              
 -109.64              0.62418              
 -109.66              0.67221              
 -109.68              0.72453              
 -109.7               0.78684              
 -109.72              0.85461              
 -109.74              0.95197              
 -109.76              1.06998              
 -109.78              1.22241              
 -109.8               1.36289              
 -109.82              1.53031              
 -109.84              1.73311              
 -109.86              1.887                
 -109.88              2.03951              
 -109.9               2.19028              
 -109.92              2.28099              
 -109.94              2.37074              
 -109.96              2.41672              
 -109.98              2.40449              
 -110.                2.33174              
 -110.02              2.22582              
 -110.04              2.14257              
 -110.06              2.05478              
 -110.08              1.96392              
 -110.1               1.91681              
 -110.12              1.8826               
 -110.14              1.87888              
 -110.16              1.90321              
 -110.18              1.96492              
 -110.2               2.05471              
 -110.22              2.16663              
 -110.24              2.32858              
 -110.26              2.53218              
 -110.28              2.7841               
 -110.3               3.10747              
 -110.32              3.42321              
 -110.34              3.71736              
 -110.36              3.91684              
 -110.38              4.07557              
 -110.4               4.24328              
 -110.42              4.29864              
 -110.44              4.23953              
 -110.46              4.12152              
 -110.48              3.94011              
 -110.5               3.73098              
 -110.52              3.5317               
 -110.54              3.28843              
 -110.56              3.01016              
 -110.58              2.77342              
 -110.6               2.5845               
 -110.62              2.38409              
 -110.64              2.20235              
 -110.66              2.04123              
 -110.68              1.905                
 -110.7               1.79206              
 -110.72              1.66783              
 -110.74              1.54818              
 -110.76              1.46031              
 -110.78              1.38969              
 -110.8               1.32268              
 -110.82              1.26178              
 -110.84              1.21232              
 -110.86              1.15703              
 -110.88              1.11292              
 -110.9               1.07555              
 -110.92              1.03365              
 -110.94              0.99859              
 -110.96              0.96544              
 -110.98              0.92639              
 -111.                0.88720              
 -111.02              0.84419              
 -111.04              0.80524              
 -111.06              0.78515              
 -111.08              0.76813              
 -111.1               0.76370              
 -111.12              0.78002              
 -111.14              0.81555              
 -111.16              0.86475              
 -111.18              0.91916              
 -111.2               0.96927              
 -111.22              1.02123              
 -111.24              1.07535              
 -111.26              1.14253              
 -111.28              1.24709              
 -111.3               1.36301              
 -111.32              1.51088              
 -111.34              1.67183              
 -111.36              1.86184              
 -111.38              2.04953              
 -111.4               2.23633              
 -111.42              2.45061              
 -111.44              2.5998               
 -111.46              2.73428              
 -111.48              2.85692              
 -111.5               2.92278              
 -111.52              2.93692              
 -111.54              2.90252              
 -111.56              2.86552              
 -111.58              2.83647              
 -111.6               2.82369              
 -111.62              2.86902              
 -111.64              2.99317              
 -111.66              3.13037              
 -111.68              3.24393              
 -111.7               3.32841              
 -111.72              3.39362              
 -111.74              3.44017              
 -111.76              3.4436               
 -111.78              3.40455              
 -111.8               3.36742              
 -111.82              3.34013              
 -111.84              3.31737              
 -111.86              3.31793              
 -111.88              3.34861              
 -111.9               3.46561              
 -111.92              3.60776              
 -111.94              3.77155              
 -111.96              3.96537              
 -111.98              4.11512              
 -112.                4.24343              
 -112.02              4.36281              
 -112.04              4.45218              
 -112.06              4.49299              
 -112.08              4.36223              
 -112.1               4.17505              
 -112.12              3.95077              
 -112.14              3.68568              
 -112.16              3.42502              
 -112.18              3.15248              
 -112.2               2.85851              
 -112.22              2.59705              
 -112.24              2.37452              
 -112.26              2.18737              
 -112.28              2.01103              
 -112.3               1.86722              
 -112.32              1.77381              
 -112.34              1.66616              
 -112.36              1.52669              
 -112.38              1.41912              
 -112.4               1.32857              
 -112.42              1.2557               
 -112.44              1.20177              
 -112.46              1.15175              
 -112.48              1.11089              
 -112.5               1.07836              
 -112.52              1.05178              
 -112.54              1.03487              
 -112.56              1.02314              
 -112.58              1.01481              
 -112.6               1.01397              
 -112.62              1.02489              
 -112.64              1.04044              
 -112.66              1.06499              
 -112.68              1.10804              
 -112.7               1.18007              
 -112.72              1.26572              
 -112.74              1.39663              
 -112.76              1.52581              
 -112.78              1.63734              
 -112.8               1.73686              
 -112.82              1.81498              
 -112.84              1.86742              
 -112.86              1.86966              
 -112.88              1.80497              
 -112.9               1.72912              
 -112.92              1.63765              
 -112.94              1.53367              
 -112.96              1.43819              
 -112.98              1.32673              
 -113.                1.21148              
 -113.02              1.11255              
 -113.04              1.0435               
 -113.06              0.99042              
 -113.08              0.93836              
 -113.1               0.89985              
 -113.12              0.86480              
 -113.14              0.83378              
 -113.16              0.80512              
 -113.18              0.76385              
 -113.2               0.72224              
 -113.22              0.68852              
 -113.24              0.66203              
 -113.26              0.63521              
 -113.28              0.61736              
 -113.3               0.61028              
 -113.32              0.6091               
 -113.34              0.61533              
 -113.36              0.61615              
 -113.38              0.60421              
 -113.4               0.57874              
 -113.42              0.55191              
 -113.44              0.53248              
 -113.46              0.52485              
 -113.48              0.52033              
 -113.5               0.51843              
 -113.52              0.53151              
 -113.54              0.54823              
 -113.56              0.56123              
 -113.58              0.57245              
 -113.6               0.57937              
 -113.62              0.58451              
 -113.64              0.58457              
 -113.66              0.61429              
 -113.68              0.65231              
 -113.7               0.69340              
 -113.72              0.7497               
 -113.74              0.80350              
 -113.76              0.84636              
 -113.78              0.88999              
 -113.8               0.93923              
 -113.82              0.99012              
 -113.84              1.0876               
 -113.86              1.20327              
 -113.88              1.32137              
 -113.9               1.46355              
 -113.92              1.63916              
 -113.94              1.84622              
 -113.96              2.06969              
 -113.98              2.38972              
 -114.                2.70298              
 -114.02              3.03003              
 -114.04              3.42124              
 -114.06              3.75733              
 -114.08              4.04797              
 -114.1               4.3009               
 -114.12              4.49071              
 -114.14              4.52471              
 -114.16              4.35691              
 -114.18              4.1444               
 -114.2               3.9623               
 -114.22              3.75826              
 -114.24              3.60303              
 -114.26              3.47792              
 -114.28              3.30848              
 -114.3               3.17402              
 -114.32              3.07965              
 -114.34              2.99487              
 -114.36              2.91417              
 -114.38              2.82001              
 -114.4               2.7126               
 -114.42              2.59734              
 -114.44              2.48578              
 -114.46              2.3527               
 -114.48              2.21576              
 -114.5               2.06457              
 -114.52              1.93038              
 -114.54              1.78345              
 -114.56              1.65094              
 -114.58              1.54908              
 -114.6               1.40107              
 -114.62              1.27999              
 -114.64              1.16998              
 -114.66              1.05487              
 -114.68              0.97195              
 -114.7               0.89672              
 -114.72              0.83249              
 -114.74              0.77090              
 -114.76              0.71555              
 -114.78              0.66357              
 -114.8               0.62907              
 -114.82              0.59364              
 -114.84              0.55260              
 -114.86              0.52013              
 -114.88              0.48194              
 -114.9               0.44473              
 -114.92              0.41730              
 -114.94              0.39158              
 -114.96              0.35169              
 -114.98              0.31430              
 -115.                0.28509              
 -115.02              0.2588               
 -115.04              0.23648              
 -115.06              0.22031              
 -115.08              0.21301              
 -115.1               0.21966              
 -115.12              0.22731              
 -115.14              0.23188              
 -115.16              0.23600              
 -115.18              0.21785              
 -115.2               0.17925              
 -115.22              0.15575              
 -115.24              0.13411              
 -115.26              0.11251              
 -115.28              0.10862              
 -115.3               0.11250              
 -115.32              0.12775              
 -115.34              0.14511              
 -115.36              0.16145              
 -115.38              0.17270              
 -115.4               0.17287              
 -115.42              0.14585              
 -115.44              0.11510              
 -115.46              0.09237              
 -115.48              0.07415              
 -115.5               0.06391              
 -115.52              0.06141              
 -115.54              0.06393              
 -115.56              0.07838              
 -115.58              0.09553              
 -115.6               0.10610              
 -115.62              0.11115              
 -115.64              0.10913              
 -115.66              0.09896              
 -115.68              0.08582              
 -115.7               0.07820              
 -115.72              0.07493              
 -115.74              0.07260              
 -115.76              0.07243              
 -115.78              0.07229              
 -115.8               0.07498              
 -115.82              0.07816              
 -115.84              0.07818              
 -115.86              0.07428              
 -115.88              0.06580              
 -115.9               0.06123              
 -115.92              0.05790              
 -115.94              0.04931              
 -115.96              0.04790              
 -115.98              0.05414              
 -116.                0.05793              
 -116.02              0.06418              
 -116.04              0.06663              
 -116.06              0.06525              
 -116.08              0.05979              
 -116.1               0.05613              
 -116.12              0.04988              
 -116.14              0.04787              
 -116.16              0.05287              
 -116.18              0.06125              
 -116.2               0.07079              
 -116.22              0.07805              
 -116.24              0.07529              
 -116.26              0.07259              
 -116.28              0.07082              
 -116.3               0.06525              
 -116.32              0.06127              
 -116.34              0.06527              
 -116.36              0.07995              
 -116.38              0.09526              
 -116.4               0.10917              
 -116.42              0.11727              
 -116.44              0.11725              
 -116.46              0.11428              
 -116.48              0.10617              
 -116.5               0.09467              
 -116.52              0.08676              
 -116.54              0.08667              
 -116.56              0.09055              
 -116.58              0.09298              
 -116.6               0.09485              
 -116.62              0.09250              
 -116.64              0.08598              
 -116.66              0.06715              
 -116.68              0.04730              
 -116.7               0.03318              
 -116.72              0.02953              
 -116.74              0.04175              
 -116.76              0.06970              
 -116.78              0.09632              
 -116.8               0.11939              
 -116.82              0.13368              
 -116.84              0.13435              
 -116.86              0.11681              
 -116.88              0.08987              
 -116.9               0.06774              
 -116.92              0.04531              
 -116.94              0.03317              
 -116.96              0.03331              
 -116.98              0.03637              
 -117.                0.04263              
 -117.02              0.05300              
 -117.04              0.06595              
 -117.06              0.07564              
 -117.08              0.07793              
 -117.1               0.07806              
 -117.12              0.07799              
 -117.14              0.07818              
 -117.16              0.07506              
 -117.18              0.07264              
 -117.2               0.07247              
 -117.22              0.07042              
 -117.24              0.06717              
 -117.26              0.06388              
 -117.28              0.06000              
 -117.3               0.05757              
 -117.32              0.05458              
 -117.34              0.04382              
 -117.36              0.02736              
 -117.38              0.01200              
 -117.4              -0.00131              
 -117.42             -0.01211              
 -117.44             -0.01538              
 -117.46             -0.01195              
##END=
