##TITLE=              31P MAS NMR spectrum of as-made VPI-5 (hydrated) at 370 K
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             Rocha et al. J. Am. Chem. Soc., 114, 4884-4888 (1992) Figure 3
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University
##LONG DATE=          2020/07/22 14:30:33
##SOURCE REFERENCE=   VFI-31P-Rocha-1992-asmade-370K
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              VFI
##NAMES=              VPI-5
##SAMPLE DESCRIPTION= VPI-5, as-made, hydrated, 370 K
##TEMPERATURE=        370 K

$$Bibliographic information 
##$AUTHORS=           Rocha, J., Kolodziejski, W., He, H., Klinowski, J.
##$TITLE=             Solid-State NMR Studies of Hydrated Porous Aluminophosphate VPI-5
##$JOURNAL=           Journal of the American Chemical Society
##$VOLUME=            114
##$PAGES=             4884-4888
##$YEAR=              1992
##$DOI=               10.1021/ja00038a064
##$FIGURE=            Figure 3

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         2
##$PEAK LABELS=        P1         P2        
##$PEAK TSITES=        T2         T1        
##$PEAK POSITIONS=    -31.7271   -25.5821   
##$PEAK AREAS=         1.         2.        
##$PEAK WIDTHS=        1.51129    1.59623   
##$PEAK SHAPES=        0.24457    0.24457   
##$NUMBERING REF=     de Onate Martinez et al. Microporous Mesoporous Mater., 22, 127-134 (1998)
##$ASSIGN REF=        de Onate Martinez et al. Microporous Mesoporous Mater., 22, 127-134 (1998) Table 2
##$ASSIGN METHOD=     relative intensities
##$COMMENT=           Peak assignments based on relative peak areas

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^31P
##.OBSERVE FREQUENCY= 162.0
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     8000-12000

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=             -14.4                 
##LASTX=              -41.7                 
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            274
##FIRSTY=             -0.01775              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
 -14.4               -0.01775              
 -14.5               -0.01681              
 -14.6               -0.01675              
 -14.7               -0.01678              
 -14.8               -0.01675              
 -14.9               -0.01699              
 -15.                -0.01804              
 -15.1               -0.01942              
 -15.2               -0.02042              
 -15.3               -0.01948              
 -15.4               -0.01860              
 -15.5               -0.01780              
 -15.6               -0.01676              
 -15.7               -0.01805              
 -15.8               -0.02005              
 -15.9               -0.02044              
 -16.                -0.02033              
 -16.1               -0.02037              
 -16.2               -0.02035              
 -16.3               -0.02036              
 -16.4               -0.02003              
 -16.5               -0.01833              
 -16.6               -0.01758              
 -16.7               -0.01867              
 -16.8               -0.01972              
 -16.9               -0.02026              
 -17.                -0.02038              
 -17.1               -0.02011              
 -17.2               -0.01791              
 -17.3               -0.01677              
 -17.4               -0.01676              
 -17.5               -0.01684              
 -17.6               -0.01580              
 -17.7               -0.01421              
 -17.8               -0.01484              
 -17.9               -0.01643              
 -18.                -0.01686              
 -18.1               -0.01672              
 -18.2               -0.01714              
 -18.3               -0.01842              
 -18.4               -0.01977              
 -18.5               -0.02037              
 -18.6               -0.01959              
 -18.7               -0.01606              
 -18.8               -0.01078              
 -18.9               -0.00721              
 -19.                -0.00582              
 -19.1               -0.00779              
 -19.2               -0.00956              
 -19.3               -0.00968              
 -19.4               -0.00814              
 -19.5               -0.00624              
 -19.6               -0.00592              
 -19.7               -0.00624              
 -19.8               -0.00727              
 -19.9               -0.00857              
 -20.                -0.01034              
 -20.1               -0.01146              
 -20.2               -0.01015              
 -20.3               -0.00966              
 -20.4               -0.00857              
 -20.5               -0.00678              
 -20.6               -0.00603              
 -20.7               -0.00600              
 -20.8               -0.00601              
 -20.9               -0.00601              
 -21.                -0.00601              
 -21.1               -0.00601              
 -21.2               -0.00601              
 -21.3               -0.00599              
 -21.4               -0.00609              
 -21.5               -0.00490              
 -21.6               -0.00169              
 -21.7                0.00098              
 -21.8                0.00246              
 -21.9                0.00352              
 -22.                 0.00312              
 -22.1                0.00292              
 -22.2                0.00365              
 -22.3                0.00597              
 -22.4                0.00932              
 -22.5                0.01251              
 -22.6                0.01464              
 -22.7                0.01543              
 -22.8                0.01553              
 -22.9                0.01543              
 -23.                 0.01674              
 -23.1                0.01930              
 -23.2                0.02148              
 -23.3                0.02357              
 -23.4                0.02594              
 -23.5                0.02944              
 -23.6                0.03379              
 -23.7                0.03927              
 -23.8                0.04510              
 -23.9                0.05592              
 -24.                 0.06920              
 -24.1                0.08421              
 -24.2                0.10528              
 -24.3                0.13965              
 -24.4                0.19281              
 -24.5                0.27491              
 -24.6                0.38913              
 -24.7                0.49474              
 -24.8                0.58839              
 -24.9                0.66920              
 -25.                 0.76112              
 -25.1                0.85499              
 -25.2                0.92860              
 -25.3                0.98808              
 -25.4                1.03034              
 -25.5                1.05778              
 -25.6                1.06533              
 -25.7                1.04789              
 -25.8                1.0064               
 -25.9                0.96354              
 -26.                 0.89511              
 -26.1                0.80827              
 -26.2                0.71043              
 -26.3                0.59299              
 -26.4                0.48568              
 -26.5                0.40877              
 -26.6                0.346                
 -26.7                0.29559              
 -26.8                0.25116              
 -26.9                0.21467              
 -27.                 0.17877              
 -27.1                0.14891              
 -27.2                0.12628              
 -27.3                0.10492              
 -27.4                0.08691              
 -27.5                0.07048              
 -27.6                0.05825              
 -27.7                0.04885              
 -27.8                0.04059              
 -27.9                0.03411              
 -28.                 0.02940              
 -28.1                0.02809              
 -28.2                0.02786              
 -28.3                0.02627              
 -28.4                0.02329              
 -28.5                0.02120              
 -28.6                0.02084              
 -28.7                0.02090              
 -28.8                0.02088              
 -28.9                0.02088              
 -29.                 0.02089              
 -29.1                0.02087              
 -29.2                0.02079              
 -29.3                0.01856              
 -29.4                0.01512              
 -29.5                0.01368              
 -29.6                0.01397              
 -29.7                0.01708              
 -29.8                0.02016              
 -29.9                0.02265              
 -30.                 0.02651              
 -30.1                0.03277              
 -30.2                0.04401              
 -30.3                0.05947              
 -30.4                0.07965              
 -30.5                0.10035              
 -30.6                0.13139              
 -30.7                0.16749              
 -30.8                0.21565              
 -30.9                0.26927              
 -31.                 0.32762              
 -31.1                0.38741              
 -31.2                0.43803              
 -31.3                0.48837              
 -31.4                0.53432              
 -31.5                0.56547              
 -31.6                0.57978              
 -31.7                0.58083              
 -31.8                0.56422              
 -31.9                0.54201              
 -32.                 0.51523              
 -32.1                0.47936              
 -32.2                0.44356              
 -32.3                0.39647              
 -32.4                0.35015              
 -32.5                0.30560              
 -32.6                0.25738              
 -32.7                0.21554              
 -32.8                0.17369              
 -32.9                0.14063              
 -33.                 0.11539              
 -33.1                0.09365              
 -33.2                0.07765              
 -33.3                0.06466              
 -33.4                0.05458              
 -33.5                0.04592              
 -33.6                0.03852              
 -33.7                0.03367              
 -33.8                0.02887              
 -33.9                0.02624              
 -34.                 0.02432              
 -34.1                0.02197              
 -34.2                0.02091              
 -34.3                0.02089              
 -34.4                0.02087              
 -34.5                0.02092              
 -34.6                0.01979              
 -34.7                0.01727              
 -34.8                0.01564              
 -34.9                0.01547              
 -35.                 0.01549              
 -35.1                0.01559              
 -35.2                0.01521              
 -35.3                0.01821              
 -35.4                0.02088              
 -35.5                0.01977              
 -35.6                0.01649              
 -35.7                0.01325              
 -35.8                0.01199              
 -35.9                0.01190              
 -36.                 0.01192              
 -36.1                0.01193              
 -36.2                0.01187              
 -36.3                0.01232              
 -36.4                0.01321              
 -36.5                0.01369              
 -36.6                0.01372              
 -36.7                0.01373              
 -36.8                0.01344              
 -36.9                0.01265              
 -37.                 0.01199              
 -37.1                0.01207              
 -37.2                0.01319              
 -37.3                0.01514              
 -37.4                0.01554              
 -37.5                0.01549              
 -37.6                0.01552              
 -37.7                0.01526              
 -37.8                0.01393              
 -37.9                0.01134              
 -38.                 0.00782              
 -38.1                0.00559              
 -38.2                0.00864              
 -38.3                0.01096              
 -38.4                0.01183              
 -38.5                0.01260              
 -38.6                0.01428              
 -38.7                0.01524              
 -38.8                0.01687              
 -38.9                0.01952              
 -39.                 0.01928              
 -39.1                0.01657              
 -39.2                0.01556              
 -39.3                0.01550              
 -39.4                0.01551              
 -39.5                0.0155               
 -39.6                0.01554              
 -39.7                0.01535              
 -39.8                0.01677              
 -39.9                0.01958              
 -40.                 0.02090              
 -40.1                0.02087              
 -40.2                0.02053              
 -40.3                0.01806              
 -40.4                0.01569              
 -40.5                0.01545              
 -40.6                0.01567              
 -40.7                0.01768              
 -40.8                0.02034              
 -40.9                0.02099              
 -41.                 0.02118              
 -41.1                0.02243              
 -41.2                0.02270              
 -41.3                0.02234              
 -41.4                0.02136              
 -41.5                0.02250              
 -41.6                0.02522              
 -41.7                0.02628              
##END=
