Database of Zeolite Structures
 
Framework Type APC
31P MAS NMR spectrum of as-made AlPO-H3 (hydrated)


Note: Toggle plots by clicking on the legend


Peak
Q-type
Chemical Shift
Relative
Peak Width
Peak Shape
Label
(ppm)
Peak Area
(ppm)
(x)L (1-x)G
A
Q4(4Al)
-26.14
1.000
1.59
0.367
B
Q4(4Al)
-24.06
1.000
1.32
0.367



References
Spectrum

  Authors: Canesson, L., Arcon, I., Caldarelli, S. and Tuel, A.
  Title: Synthesis and characterization of cobalt-containing hydrated aluminophosphate molecular sieves CoAPO(4)-H3
  Reference: Microporous Mesoporous Mat., 26, 117-131 (1998)
  Figure: Figure 6a  

Crystal Structure

  Authors: Pluth, J.J. and Smith, J.V.
  Title: Hydrated aluminophosphate (AlPO4ยท1.5H2O) with PO4, AlO4 and AlO4(H2O)2 groups and encapsulated water
  Reference: Acta Crystallogr., C42, 1118-1120 (1986)

Digitization and Modeling of Spectrum

  To reference this collection of solid-state NMR spectra, we suggest:
  Authors: Brouwer, D.H. and White, A.L.
  Title: A comprehensive collection of solid-state 31P NMR spectra of aluminophosphate zeolites.
  Reference: Microporous Mesoporous Mat., 337, 111934 (2022)
DOI: 10.1016/j.micromeso.2022.111934
Spectrum information

  Obs. freq. 162 MHz (Field = 9.4 Tesla)
  Pulse sequence single pulse
  MAS frequency 14 kHz
  Spectrum Digitized and processed by Brouwer Lab, Redeemer University
  Data processing Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook
 
  CommentPeak assignments are not available

Chemical Formula

  [Al - P - O]-APC

Downloads

  Download digitized spectrum in JCAMP-DX format
(This file includes also the data listed on this page)
  Download all lines from the above plot in .csv format
(This file contains only the plotted data)