NON-EUO-NES: DO Family

Intergrowth Family NON-EUO-NES

Periodic Building Unit


Periodic Building Unit (PerBU):	NON layer

Layer symmetry	Cmm(m)

2D cell parameters	a = 13.94 Å	b = 22.86 Å	gamma = 90°

Connector

	Unit	EUO chain

		Adjacent chains in a connecting layer are shifted by 1/2 a with respect to one another

References
	Marler, B., Daniels, P. and Sañé i Muné, J.
		"Synthesis and structure of RUB-35, a disordered material of the EUO-NES-NON family"
		Microporous Mesoporous Mater., 64, 185-201 (2003)

Connectivity pattern

Examples

The layers are stacked along the [001] direction using the following connectivity patterns

Symmetry Operation^*	Translation^*	Comment	Image
	1/2 a	direct connection
	1/2 a	connection via EUO chains

^* relative to the previous layer


Effect on channel system
	The presence of EUO-chain connections creates a 10-ring channel along the [100] direction. In Polymorph NON (direct connections only), there is no channel system (only cages). In Polymorph EUO (alternating direct and EUO-chain connections) there is a 1-dimensional channel system with side pockets along [100]. In Polymorph NES (only EUO-chain connections), there is a 2-dimensional channel system perpendicular to [010]. All [hkl] directions given here refer to the coordinate system shown on the right.

Simplest ordered end members

Connectors are shown in light blue.
Adjacent PerBUs generated by the same connectivity pattern (with or without connectors in between) are shown with different shades of the same color for clarity.


Polymorph NON

Cell Parameters:	orthorhombic	F m m m: (# 69)
	a = 22.8620 Å	b = 15.6560 Å	c = 13.9350 Å
	α = 90.000°	β = 90.000°	γ = 90.000°
	Volume =	4987.7 Å³
Framework Density (FD_Si):	17.6

	Ring sizes (# T-atoms):	6 5 4
	Channel dimensionality:	Topological (pore opening > 6-ring): 0-dimensional

Maximum diameter of a sphere:
	that can be included	6.5 Å
	that can diffuse along	a: 2.27 Å	b: 2.3 Å	c: 2.3 Å
		addional volume data

Composite Building Units:


	non

In this space group and setting, the PerBUs are stacked along [010]

	Note: This polymorph corresponds to the ordered framework NON


Polymorph EUO

Cell Parameters:	orthorhombic	C m m e: (# 67)
	a = 13.9010 Å	b = 22.8610 Å	c = 20.5820 Å
	α = 90.000°	β = 90.000°	γ = 90.000°
	Volume =	6540.8 Å³
Framework Density (FD_Si):	17.1

	Ring sizes (# T-atoms):	10 6 5 4
	Channel dimensionality:	Topological (pore opening > 6-ring): 1-dimensional

Maximum diameter of a sphere:
	that can be included	7 Å
	that can diffuse along	a: 4.99 Å	b: 1.98 Å	c: 2.5 Å
		addional volume data

Composite Building Units:


	cas		non

In this space group and setting, the PerBUs are stacked along [001]

	Note: This polymorph corresponds to the ordered framework EUO


Polymorph NES

Cell Parameters:	orthorhombic	F m m m: (# 69)
	a = 26.0600 Å	b = 13.8840 Å	c = 22.8600 Å
	α = 90.000°	β = 90.000°	γ = 90.000°
	Volume =	8271.1 Å³
Framework Density (FD_Si):	16.4

	Ring sizes (# T-atoms):	10 6 5 4
	Channel dimensionality:	Topological (pore opening > 6-ring): 2-dimensional

Maximum diameter of a sphere:
	that can be included	7.04 Å
	that can diffuse along	a: 5.07 Å	b: 5.07 Å	c: 2.06 Å
		addional volume data

Composite Building Units:


cas	non	ton

In this space group and setting, the PerBUs are stacked along [100]

	Note: This polymorph corresponds to the ordered framework NES

Disorder Examples



	Simple example of a random stacking of NON and EUO polymorphs

	The 10-ring channels of the EUO slabs are not blocked by the NON slabs.



	Simple example of a random stacking of EUO and NES polymorphs

	The 2nd dimension of the NES channel system is blocked by the EUO slabs.