RTH-ITE: DO Family

Intergrowth Family RTH-ITE

Periodic Building Unit


Periodic Building Unit (PerBU):	RTH layer

Layer symmetry	C 1 m (1)

2D cell parameters	a = 20.53 Å	b = 9.76 Å	gamma = 90°

References
	Wagner, P., Nakagawa, Y., Lee, G.S., Davis, M.E., Elomari, S., Medrud, R.C. and Zones, S.I.
		"Guest/host relationships in the synthesis of the novel cage-based zeolites SSZ-35, SSZ-36 and SSZ-39"
		J. Am. Chem. Soc., 122, 263-273 (2000)

Connectivity pattern

Examples

The layers are stacked along the [001] direction using the following connectivity patterns

Symmetry Operation^*	Translation^*	Comment	Image
i	None	one inversion center shown as an open circle in the example
m	None	mirrow plane shown as a solid line in the example

^* relative to the previous layer


Effect on channel system
	The disorder does not block the channel system

Simplest ordered end members

The color of each layer reflects the symmetry/translation operation used to generate it from the previous layer (see table above).


Polymorph RTH

Cell Parameters:	monoclinic	C 1 2/m 1: (# 12)
	a = 9.7620 Å	b = 20.5300 Å	c = 9.9960 Å
	α = 90.000°	β = 96.897°	γ = 90.000°
	Volume =	1988.9 Å³
Framework Density (FD_Si):	16.1

	Ring sizes (# T-atoms):	8 6 5 4
	Channel dimensionality:	Topological (pore opening > 6-ring): 2-dimensional

Maximum diameter of a sphere:
	that can be included	8.18 Å
	that can diffuse along	a: 4.14 Å	b: 1.67 Å	c: 2.76 Å
		addional volume data

Composite Building Units:


	rth

In this space group and setting, the PerBUs are stacked along [001]
Adjacent layers generated by the same connectivity pattern (same basic color) are shown with different shades for clarity.

	Note: This polymorph corresponds to the ordered framework RTH


Polymorph ITE

Cell Parameters:	orthorhombic	C m c m: (# 63)
	a = 20.7530 Å	b = 9.8040 Å	c = 20.0090 Å
	α = 90.000°	β = 90.000°	γ = 90.000°
	Volume =	4071.1 Å³
Framework Density (FD_Si):	15.7

	Ring sizes (# T-atoms):	8 6 5 4
	Channel dimensionality:	Topological (pore opening > 6-ring): 2-dimensional

Maximum diameter of a sphere:
	that can be included	8.3 Å
	that can diffuse along	a: 2.07 Å	b: 4.21 Å	c: 2.8 Å
		addional volume data

Composite Building Units:


	rth

In this space group and setting, the PerBUs are stacked along [001]
Adjacent layers generated by the same connectivity pattern (same basic color) are shown with different shades for clarity.

	Note: This polymorph corresponds to the ordered framework ITE