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AlPO-25
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AlPO-25
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AlPO-25
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Reference Material
Framework Type
ATV
Reference Material
Material Name:
AlPO-25
Chemical Formula:
[
Al
12
P
12
O
48
]
-
ATV
Unit Cell:
orthorhombic
A e m m (# )
a'
= 9.4490 Å
b'
= 15.2030 Å
c'
= 8.4080 Å
α' = 90.000°
β' = 90.000°
γ' = 90.000°
(Relationship to unit cell of Framework Type: a' = c, b' = b, c' = a)
Framework Density:
19.9 T/1000 Å
3
Channels:
[001]
8
3.0 x 4.9*
Dimensionality
Sorption (molecular cross section > 3.4Å):
0-dimensional
Topological (pore opening > 6-ring):
1-dimensional
References:
Richardson Jr., J.W., Smith, J.V. and Pluth, J.J.
"AlPO
4
-25: Framework topology, topotactic transformation from AlPO
4
-21 and high-low displacive transition"
J. Phys. Chem.
,
94
, 3365-3367 (1990)
Name and Code derivation:
A
lPO
4
-25 (
t
wenty-fi
v
e)
ATV
Limiting Rings
8-ring viewed along [001]
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IZA-SC
)