Database of Zeolite Structures
 
Framework Type ZON
31P MAS NMR spectrum of as-made AlPO-ZON (with fluoride and tetramethylammonium template)


Note: Toggle plots by clicking on the legend

Peak
T site
Q-type
Chemical Shift
Relative
Peak Width
Peak Shape
Assigment
(topological)
(ppm)
Peak Area
(ppm)
(x)L (1-x)G
P2
T1
Q4(4Al)
-32.11
1.000
1.66
0.791
P1
T2
Q4(4Al)
-20.90
1.000
1.31
0.791
P3
T3
Q4(4Al)
-19.53
1.000
1.38
0.791
P4
T4
Q4(4Al)
-16.74
1.000
1.29
0.791


References
Spectrum

  Authors: Roux, M., Marichal, C., Le Meins, J.M., Baerlocher, C., Chezeau, J.M.
  Title: Solid state NMR and X-ray diffraction study of three forms of the aluminophosphate AlPO4-ZON
  Reference: Microporous Mesoporous Mater., 63, 163-176 (2003)
  Figure: Figure 3b  

Peak Assignment

  Authors: Roux, M., Marichal, C., Le Meins, J.M., Baerlocher, C., Chezeau, J.M.
  Title: Solid state NMR and X-ray diffraction study of three forms of the aluminophosphate AlPO4-ZON
  Reference: Microporous Mesoporous Mater., 63, 163-176 (2003)
  Method: 2D correlation NMR
  Figure: Figure 3a and 4a  

Crystal Structure

  Authors: Akporiaye, D.E., Fjellvåg, H., Halvorsen, E.N., Hustveit, J., Karlsson, A. and Lillerud, K.P.
  Title: UiO-7: A new aluminophosphate phase solved by simulated annealing and high-resolution powder diffraction
  Reference: J. Phys. Chem., 100, 16641-16646 (1996)

Digitization and Modeling of Spectrum

  To reference this collection of solid-state NMR spectra, we suggest:
  Authors: Brouwer, D.H. and White, A.L.
  Title: A comprehensive collection of solid-state 31P NMR spectra of aluminophosphate zeolites.
  Reference: Microporous Mesoporous Mat., 337, 111934 (2022)
Spectrum information

  Obs. freq. 161.9 MHz (Field = 9.4 Tesla)
  Pulse sequence single pulse
  MAS frequency 3.5-8 kHz
  Spectrum Digitized and processed by Brouwer Lab, Redeemer University
  Data processing Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook
 
  CommentSpectrum was acquired with simultaneous 1H and 27Al decoupling. Peak assignments are based on a 2D 31P/31P correlation spectrum and a 19F/31P cross polarization spectrum.

Chemical Formula

  [Al - P - O]-ZON

Downloads

  Download digitized spectrum in JCAMP-DX format
(This file includes also the data listed on this page)
  Download all lines from the above plot in .csv format
(This file contains only the plotted data)

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