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PST-6
NMR
Phosphorus-31
PST-6, dehydrated
PST-6, hydrated
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PST-6
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Reference Material
Framework Type
PSI
Reference Material
Material Name:
PST-6
Chemical Formula:
[
Al
72
P
72
O
288
]
-
PSI
Unit Cell:
orthorhombic
P b a 2 (# 32)
a'
= 38.2793 Å
b'
= 22.4638 Å
c'
= 8.3620 Å
α' = 90.000°
β' = 90.000°
γ' = 90.000°
Framework Density:
20.0 T/1000 Å
3
Channels:
[001]
10
5.0 x 5.6* | [001]
8
2.0 x 2.5*
Dimensionality
Sorption (molecular cross section > 3.4Å):
1-dimensional
Topological (pore opening > 6-ring):
1-dimensional
References:
Lee, J.K., Turrina, A., Zhu, L., Seo, S., Zhang, D., Cox, P.A., Wright, P.A., Qiu, S., Hong, S.B.
"An aluminophosphate molecular sieve with 36 crystallographically distinct tetrahedral sites"
Angew. Chem. Int. Ed.
,
53
, 7480-7483 (2014)
Name and Code derivation:
P
O
ST
ECH, Pohang (Korea) - six
P
ST-6 (
si
x)
PSI
Limiting Rings
10-ring viewed along [001]
8-ring viewed along [001]
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IZA-SC
)