Database of Zeolite Structures
 

Framework Type -HOS
Reference Material
  Material Name: HPM-16    
 
Chemical Formula:		  
|MEPI11.65F10|1 [Si95.36Ge40.64O276]1--HOS
MEPI = C9H17N2+ = 1-methyl-2-ethytl-3-n-propylimidazolium
= 2-ethyl-1-methyl-3-propylimidazol-1-ium
SMILES: C1=C[N](=C([N]1C)CC)CCC   Images:  stick or 3D		  
   
Unit Cell: 		 
orthorhombic
 C m m m (# 65)
    a' = 14.2205 Å b' = 50.9600 Å c' = 12.7320 Å  
    α' = 90.000° β' = 90.000° γ' = 90.000°  
   
Framework Density: 		 
14.7 T/1000 Å3
 
  
Channels: 		 
([100] 12 6.0 x 9.1 ↔ [001] 12 7.2 x 8.0 ↔ [100] 10 5.2 x 5.2 )***
Dimensionality
  Sorption (molecular cross section > 3.4Å): 3-dimensional
  Topological (pore opening > 6-ring): 3-dimensional
    Note:
Diffusion along [010] only through the 10-ring along [100] (limiting ring)
   
References:
  Gao, Z. R., Balestra, S. R. G., Li, J.; Camblor, M. A.
  "HPM-16, a Stable Interrupted Zeolite with a Multidimensional Mixed Medium–Large Pore System Containing Supercages."
Angew. Chem. Int. Ed., 60, 20249-20252 (2021)
 
  
Name and Code derivation:
    Nanostructured Hybrid, Biohybrid and Porous Materials Group - sixteen
  HPM-16 (one six)
  -HOS
Limiting Rings
 
12-ring viewed along [100]

12-ring viewed along [001]

10-ring viewed along [100]

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