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Reference Material
Framework Type
CZP
Reference Material
Material Name:
Chiral Zincophosphate
Chemical Formula:
|
Na
12
(H
2
O)
12
|
[
Zn
12
P
12
O
48
]
-
CZP
Unit Cell:
§
hexagonal
P 6
1
2 2 (# 178)
a'
= 10.4800 Å
b'
= 10.4800 Å
c'
= 15.0890 Å
α' = 90.000°
β' = 90.000°
γ' = 120.000°
Framework Density:
16.7 T/1000 Å
3
Channels:
[001]
12
3.8 x 7.2* (highly distorted 12-ring)
Dimensionality
Sorption (molecular cross section > 3.4Å):
1-dimensional
Topological (pore opening > 6-ring):
1-dimensional
References:
Rajic, N., Logar, N.Z. and Kaucic, V.
"A novel open framework zincophosphate: Synthesis and characterization"
Zeolites
,
15
, 672-678 (1995)
Material name:
Chiral Zincophosphate
Chemical formula:
[
Zn
12
P
12
O
48
]
-
CZP
§
Harrison, W.T.A., Gier, T.E., Stucky, G.D., Broach, R.W. and Bedard, R.A.
"NaZnPO4·H2O, an open-framework sodium zincophosphate with a new chiral tetrahedral framework topology"
Chem. Mater.
,
8
, 145-151 (1996)
Name and Code derivation:
C
hiral
Z
inco
p
hosphate
CZP
§
Chemical Formula and Unit Cell taken from the reference marked with this sign
Limiting Rings
distorted 12-ring viewed along [001]
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IZA-SC
)